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Miyasaka, K., Watanabe, K., Jojima, E., Aida, H., Sumita, M., & Ishikawa, K. (1982a). Electrical conductivity of carbon-polymer composites as a function of carbon content. Journal of Materials Science, 17(6), 1610-1616. Molau, G. E., & Keskkula, H. (1966). Heterogeneous polymer systems. IV. Mechanism of rubber particle formation in rubber-modified vinyl polymers. Journal of Polymer Science Part A-1: Polymer Chemistry, 4(6), 1595-1607. Montes, J. M., Cuevas, F. G., Rodriguez, J. A., & Herrera, E. J. (2005). Electrical conductivity of sintered powder compacts. Powder Metallurgy, 48(4), 343-344. Moon Gyu, H., & Seung Soon, I. (2001). Morphological study of conductive polyaniline/polyimide blends. I. Determination of compatibility by small-angle X-ray scattering method. Polymer, 42(17), 7449-7454. Morgan, H., Foot, P. J. S., & Brooks, N. W. (2001). The effects of composition and processing variables on the properties of thermoplastic polyaniline blends and composites. Journal of Materials Science, 36(22), 5369-5377. Moussaif, N., & Jérôme, R. (1999). Compatibilization of immiscible polymer blends (PC/PVDF) by the addition of a third polymer (PMMA): analysis of phase morphology and mechanical properties. Polymer, 40(14), 3919-3932. Munson-McGee, S. H. (1991). Estimation of the critical concentration in an anisotropic percolation network. Physical Review B (Condensed Matter), 43(4), 3331-3336. Narkis, M., Haba, Y., Segal, E., Zilberman, M., Titelman, G. I., & Siegmann, A. (2000a). Structured electrically conductive polyaniline/polymer blends. Polymers for Advanced Technologies, 11(8-12), 665-673. Narkis, M., & Vaxman, A. (1984). Resistivity behavior of filled electrically conductive crosslinked polyethylene. Journal of Applied Polymer Science, 29(5), 1639-1652. Narkis, M., Zilberman, M., & Siegmann, A. (1997). On the "curiosity" of electrically conductive melt processed doped-polyaniline/polymer blends versus carbonblack/polymer compounds. Polymers for Advanced Technologies, 8(8), 525-528. Nauman, E. B., & He, D. Q. (2001). Nonlinear diffusion and phase separation. Chemical Engineering Science, 56(6), 1999-2018. Nemirovski, N., Siegmann, A., & Narkis, M. (1995). Morphology of ternary immiscible polymer blends. Journal of Macromolecular Science - Physics, B34(4), 459-475. Netz, R. R., & Andelman, D. (2003). Neutral and charged polymers at interfaces. Physics Reports, 380(1-2), 1-95. Nguyen, T. T., & Shklovskii, B. I. (2001). Overcharging of a macroion by an oppositely charged polyelectrolyte. Physica A, 293(3-4), 324-338. Nicol, E., Habib-Jiwan, J. L., & Jonas, A. M. (2003). Polyelectrolyte Multilayers as Nanocontainers for Functional Hydrophilic Molecules. Langmuir, 19(15), 6178-6186. Nicolau, Y. F. (1985). Solution deposition of thin solid compound films by a successive ioniclayer adsorption and reaction process, Sydney, NSW, Australia. 224
Niziol, J., & Laska, J. (1999). Conductivity of blends of polyaniline with PMMA and cellulose acetate: aging studies, Montpellier, France. Odijk, T. (1980). Binding of Long Flexible Chains to a Rodlike Macromolecule. Macromolecules, 13(6), 1542-1546. Omonov, T. S., Harrats, C., & Groeninckx, G. (2005). Co-continuous and encapsulated three phase morphologies in uncompatibilized and reactively compatibilized polyamide 6/polypropylene/polystyrene ternary blends using two reactive precursors. Polymer, 46(26), 12322-12336. Ong, C. H., Goh, S. H., & Chan, H. S. O. (1997). Conductive polyaniline/poly(vinylphosphonic acid) blends. Polymer Bulletin (Berlin), 39(5), 627. P. Bertrand, A. J. A. L. R. L. (2000). Ultrathin polymer coatings by complexation of polyelectrolytes at interfaces: suitable materials, structure and properties. Macromolecular Rapid Communications, 21(7), 319-348. Paloheimo, J., Laakso, K., Isotalo, H., & Stubb, H. (1995). Conductivity, thermoelectric power and field-effect mobility in self-assembled films of polyanilines and oligoanilines. Synthetic Metals, 68(3), 249-257. Panipol. (2000). Polyaniline - Processing and Applications. http://www.azom.com/details.asp?ArticleID=1197. Park, M.-K., Deng, S., & Advincula, R. C. (2005). Sustained Release Control via Photo-Cross- Linking of Polyelectrolyte Layer-by-Layer Hollow Capsules. Langmuir, 21(12), 5272- 5277. Paul, D., & Newman, S. (1978). Polymer Blends (Vol. 1, 2). New York: Academic Press. Paul, D. R., & Barlow, J. W. (1980b). Polymer Blends (or Alloys). Journal of Macromolecular Science- Reviews in Macromolecular Chemistry, C18(1), 109-168. Paul, R. K., Vijayanathan, V., & Pillai, C. K. S. (1999). Melt/solution processable conducting polyaniline: doping studies with a novel phosphoric acid ester. Synthetic Metals, 104(3), 189-195. Picart, C., Ladam, G., Senger, B., Voegel, J. C., Schaaf, P., Cuisinier, F. J. G., et al. (2001). Determination of structural parameters characterizing thin films by optical methods: A comparison between scanning angle reflectometry and optical waveguide lightmode spectroscopy. Journal of Chemical Physics, 115(2), 1086-1094. Picart, C., Lavalle, P., Hubert, P., Cuisinier, F. J. G., Decher, G., Schaaf, P., et al. (2001). Buildup mechanism for poly(L-lysine)/hyaluronic acid films onto a solid surface. Langmuir, 17(23), 7414-7424. Picart, C., Mutterer, J., Richert, L., Luo, Y., Prestwich, G. D., Schaaf, P., et al. (2002). Molecular basis for the explanation of the exponential growth of polyelectrolyte multilayers. Proceedings of the National Academy of Sciences of the United States of America, 99(20), 12531-12535. 225
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© Sepehr Ravati, 2010. UNIVERSITÉ
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DEDICATED To my parents iii
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RÉSUMÉ Cette thèse présente, po
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devenir une structure hiérarchique
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ABSTRACT This thesis presents, for
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system can be increased from 10 -15
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CONDENSÉ EN FRANÇAIS Dans ce trav
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deuxième coquille de PS. Les phase
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structures à percolation multiple
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autre sous-type de morphologie dans
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TABLE OF CONTENTS DEDICATION.......
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xxiii 2.4.1.1.1 Charged Polymer Ads
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5.3.4 Annealing Test ..............
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xxvii REFERENCES ..................
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LIST OF FIGURES xxix Figure 1-1. a)
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Figure 2-12. SEM photomicrograph of
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Figure 2-34. Schematic view of diff
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Figure 4-8. SEM micrographs of vari
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Figure 5-6. a),b) Scanning electron
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and c) triangular concentration dia
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n number of moles p concentration o
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AFM atomic force microscopy LIST OF
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PS-co-PMMA copolymer of PS and PMMA
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1.1 Introduction CHAPTER 1 - INTROD
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Figure 1-2. Human heart, longitudin
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One of the applications for porous
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On the other hand, a novel tri-cont
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2.1 Polymer Blends CHAPTER 2 - LITE
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Based on Sterling’s approximation
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Antonoff’s rule (Equation 2-13) i
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2.1.2.1 Binary Polymer Blends 2.1.2
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Some other studies(Everaert, Aerts,
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where the parameter z is dependent
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“compatibilization” was suggest
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a) λ BC A and B are matrices, b) C
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Reignier & Favis, 2000, 2003a; Reig
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measure the interfacial tension of
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a) b) Figure 2-6. Dependence of the
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Omonov et al. found double percolat
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2.1.2.2.3 Effect of Composition on
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a) b) C B A c) Figure 2-12. SEM pho
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In the case where PS is the matrix,
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Posthuma de Boer, 1999) (Kumin & Ch
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lattice, such as square lattice, wi
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magnetization, which is a function
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Polymers have long been thought of
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epoxy as a function of nanotube wei
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Figure 2-19. Approaching the percol
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Figure 2-21. Transmission electron
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Figure 2-22: Dependence of PE conti
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Figure 2-24. Plot of the total numb
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chain provides the conductive path
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2.3.1.2.1 Polyaniline One of the mo
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CoPA/LLDPE/PANI blend and a poor-qu
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Narkis and co-workers extended and
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Figure 2-31: Conductivity of PVDF/P
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organic thin films, a novel and str
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on the topic have been reported in
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succeeded in creating thin films wi
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Addition of salt to the solution of
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different from that of linear homop
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Figure 2-39. Macromolecule with a)
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polyanion such as hyaluronan (HA)(P
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2.4.1.1.7 Effect of Salt on Multila
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2.4.1.1.8 Overcompensation of the M
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important factors determining the g
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As shown in Figure 2-44, swelling a
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increasing the pH value due to a de
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CHAPTER 3 - ORGANIZATION OF THE ART
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discussed above, HDPE, PS, PMMA, an
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CHAPTER 4 - LOW PERCOLATION THRESHO
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or model which predicts where the p
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concentration threshold for the ons
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chemical and weathering resistance,
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Table 4-1. Material Characteristics
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filled with blend pellets. To facil
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4.3.6 Conductivity Measurements DC
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experimentally in this research gro
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a) b) c) d) Figure 4-4. Schematic i
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microstructure of the quaternary bl
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a) b) c) d) Figure 4-6. SEM microgr
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a) b) PVDF PS PMMA c) d) e) HDPE PS
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Uniform layers of PS and PMMA situa
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the concentration of HDPE is increa
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a) b) c) e) Figure 4-11. SEM microg
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melt-processable and contains 25 wt
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One question that should be address
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Conductivity(S/cm) Ternary Blend 1,
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phase(PMMA), the concentration of P
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(6) Virgilio, N.; Desjardins, P.; L
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ONION MORPHOLOGY HDPE PVDF PS Contr
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work described above has focused on
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thermodynamic explanation to predic
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four-point probe increases continuo
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in the rheology tests were compress
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5.3.6 Layer-by-Layer Deposition The
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prepare a polymer blend structure w
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a) b) c) Figure 5-3. Scanning elect
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spontaneously self-assembled. After
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a) b) c) d) e) f) g) h) Figure 5-5.
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Since the ultra-low surface area va
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c) a) b) Figure 5-6. a),b) Scanning
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salt to a PSS polyelectrolyte solut
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A relationship between macropore si
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close together. It is interesting t
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Figure 5-9. Mass increase (%) indic
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In this work the conductance of the
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deposited PANI layers increases unt
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(52) Guo, H. F.; Packirisamy, S.; G
Page 219 and 220: 6.2 Introduction It is well-known t
Page 221 and 222: modified version of Harkins theory(
Page 223 and 224: 6.3 Experimental 6.3.1 Materials Co
Page 225 and 226: Complex voscosity (Pa.s) 1,0E+04 1,
Page 227 and 228: 6.3.5.2 Focused Ion Beam (FIB) and
Page 229 and 230: a) c) b) d) e) f) PMMA PMMA HDPE HD
Page 231 and 232: y Harkins theory, PS will always si
Page 233 and 234: a) b) c) d) e) f) PS Figure 6-6. a)
Page 235 and 236: a) b) HDPE : black PS : grey PMMA :
Page 237 and 238: 6.4.6 Continuity, Co-continuity, an
Page 239 and 240: c) V III II I VII I IV VI Figure 6-
Page 241 and 242: Continuity Scheme (a) Figure 6-10.
Page 243 and 244: Addition of a low concentration of
Page 245 and 246: Addition of small amounts of HDPE t
Page 247 and 248: icontinuous network with the HDPE.
Page 249 and 250: Three examples are shown in Figure
Page 251 and 252: (9) Mekhilef, N.; Verhoogt, H. Poly
Page 253 and 254: structures are formed due to the co
Page 255 and 256: CONCLUSION AND RECOMMENDATIONS In t
Page 257 and 258: REFERENCES A. K. Gupta, K. R. S. (1
Page 259 and 260: Caruso, F. (2003). Hollow Inorganic
Page 261 and 262: Domenech, S. C., Bortoluzzi, J. H.,
Page 263 and 264: Geuskens, G., Gielens, J. L., Geshe
Page 265 and 266: Hou, S., Harrell, C. C., Trofin, L.
Page 267 and 268: Krass, H., Papastavrou, G., & Kurth
Page 269: Macdiarmid, A. G., Jin-Chih, C., Ha
Page 273 and 274: Reghu, M., Yoon, C. O., Yang, C. Y.
Page 275 and 276: Shirakawa, H., Louis, E. L., MacDia
Page 277 and 278: Utracki, L. A. (1991). On the visco
Page 279 and 280: Yasuda, K., Armstrong, R., & Cohen,
Page 281 and 282: literature has examined factors inf
Page 283 and 284: (Reignier & Favis, 2000, 2003a; Rei
Page 285 and 286: Table A-1.2. Interfacial tensions a
Page 287 and 288: acquisition of images with a very h
Page 289 and 290: Table A-1.3. Continuity of the PMMA
Page 291 and 292: (17) Reignier, J.; Favis, B. D., Ma
Page 293 and 294: PANI. Theoretically, the extent of
Page 295 and 296: Equation A-2.7 0( ) 0 1. 5 σ = σ
Page 297 and 298: Cumulative Mass × 10 5 (g) dipping
Page 299 and 300: of PANI, and an increase in the con
Page 301 and 302: Resistance(ohm) 1.0E+12 1.0E+11 1.0
Page 303 and 304: esistance value. Samples containing
Page 305 and 306: The results of resistance for PS/PE
Page 307 and 308: Caruso, F., & Schuler, C. (2000). E
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