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a) b - École Polytechnique de Montréal

a) b - École Polytechnique de Montréal

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g)<br />

Figure 6-5. (a) Schematic representation of the matrix/core-shell dispersed phase morphology,<br />

(b) SEM micrograph of 60/10/30 HDPE/PS/PMMA blend after extraction of PS by cyclohexane,<br />

(c) schematic representation of tri-continuous morphology (type I), (d) FIB-AFM image of<br />

40/20/40 HDPE/PS/PMMA showing tri-continuous morphology. Scan size is 25μm×25μm. The<br />

bar to the right of the FIB/AFM micrograph indicates the colours associated with the<br />

topographical height in nm, (e) schematic representation of tri-continuous(type II), (f) SEM<br />

micrograph of 30/30/40 HDPE/PS/PMMA after extraction of PS by cyclohexane, (g) schematic<br />

representation of matrix/two separate dispersed phases morphology, and (h) SEM micrograph of<br />

10/80/10 HDPE/PS/PMMA microtomed.<br />

Note that in all schematics black represents the HDPE phase, grey represents the PS phase and<br />

white represents the PMMA phase.<br />

6.4.2 Tri-continuous Morphology<br />

h)<br />

In a ternary blend with a matrix/core-shell morphology, increasing the concentration of<br />

the core phase results in the coalescence of core phases which leads to the formation of a tricontinuous<br />

morphology. In the mo<strong>de</strong>l ternary HDPE/PS/PMMA blend studied here, as predicted<br />

184

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