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a) b - École Polytechnique de Montréal

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xxiii<br />

2.4.1.1.1 Charged Polymer Adsorption ...................................................................... 71<br />

2.4.1.1.2 Polymer Adsorption on the Surface ............................................................ 73<br />

2.4.1.1.3 Adsorption of Polyelectrolytes on the Surface of a Substrate ..................... 75<br />

2.4.1.1.4 Various Mechanisms of Film Growth ......................................................... 78<br />

2.4.1.1.5 Effect of Polyelectrolyte Concentration on Multilayers ............................. 79<br />

2.4.1.1.6 Effect of Molecular Weight on Multilayers ................................................ 80<br />

2.4.1.1.7 Effect of Salt on Multilayers ....................................................................... 81<br />

2.4.1.1.8 Overcompensation of the Multilayer/Solution Interface ............................. 83<br />

2.4.1.1.8.1 Overcompensation due to Difussion of Polyelectrolytes insi<strong>de</strong><br />

Multilayers 83<br />

2.4.1.1.8.2 Overcompensation due to the Addition of Salt .................................... 85<br />

2.4.1.1.9 LbL Deposition on Curved Surfaces ........................................................... 88<br />

2.4.1.1.10 Effect of Roughness on the Multilayer Thickness .................................... 88<br />

2.4.1.1.11 Important Views on PANI/PSS LbL Adsorption ...................................... 89<br />

2.4.1.1.12 Characterization Techniques for LbL Deposited Layers .......................... 90<br />

CHAPTER 3 - ORGANIZATION OF THE ARTICLES ....................................................... 91<br />

CHAPTER 4 - LOW PERCOLATION THRESHOLD CONDUCTIVE DEVICE<br />

DERIVED FROM A FIVE-COMPONENT POLYMER BLEND ........................................ 95<br />

4.1 Abstract ......................................................................................................................... 95<br />

4.2 Introduction ................................................................................................................... 95<br />

4.3 Experimental Methods ................................................................................................ 102<br />

4.3.1 Materials ................................................................................................................. 102<br />

4.3.2 Rheological Analysis .............................................................................................. 103<br />

4.3.3 Sample Preparation ................................................................................................. 104<br />

4.3.4 Solvent Extraction ................................................................................................... 105

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