Liang, Z., Cabarcos, O. M., Allara, D. L., & Wang, Q. (2004). Hydrogen-Bonding-Directed Layer-by-Layer Assembly of Conjugated Polymers. Advanced Materials, 16(9-10), 823- 827. Liangcai, L., Ming, W., Huoming, S., Haiying, L., Qingdong, Q., & Yuanlong, D. (2001). Preparation and EIS studies on polyimi<strong>de</strong>/polyaniline blend film for corrosion protection. Polymers for Advanced Technologies, 12(11-12), 720-723. Lifshitz, E. M., Landau, L. D., & Pitaevskii, L. P. (1984). Electrodynamics of Continuous Media (Vol. 8). Lin, B., Gelves, G. A., Haber, J. A., Potschke, P., & Sundararaj, U. (2008). Electrical, morphological and rheological study of melt-mixed polystyrene/copper nanowire nanocomposites. Macromolecular Materials and Engineering, 293(Compen<strong>de</strong>x), 631- 640. Love, J. C., Estroff, L. A., Kriebel, J. K., Nuzzo, R. G., & Whitesi<strong>de</strong>s, G. M. (2005). Self- Assembled Monolayers of Thiolates on Metals as a Form of Nanotechnology. Chemical Reviews, 105(4), 1103-1170. Luciani, A., & Jarrin, J. (1996). Morphology <strong>de</strong>velopment in immiscible polymer blends. Polymer Engineering & Science, 36(12), 1619-1626. Luckham, P. F., & Klein, J. (1985). Interactions between smooth solid surfaces in solutions of adsorbing and nonadsorbing polymers in good solvent conditions. Macromolecules, 18(4), 721-728. Lutt, M., Fitzsimmons, M. R., & DeQuan, L. (1998). X-ray reflectivity study of self-assembled thin films of macrocycles and macromolecules. Journal of Physical Chemistry B, 102(2), 400-405. Luzinov, I., Pagnoulle, C., & Jerome, R. (2000). Ternary polymer blend with core-shell dispersed phases: effect of the core-forming polymer on phase morphology and mechanical properties. Polymer, 41(19), 7099-7109. Lvov, Y., Ariga, K., Ichinose, I., & Kunitake, T. (1995). Assembly of Multicomponent Protein Films by Means of Electrostatic Layer-by-Layer Adsorption. J. Am. Chem. Soc., 117(22), 6117-6123. Lvov, Y., Decher, G., & Sukhorukov, G. (1993). Assembly of thin films by means of successive <strong>de</strong>position of alternate layers of DNA and poly(allylamine). Macromolecules, 26(20), 5396-5399. Lvov, Y. M., & Decher, G. (1994). Assembly of multilayer or<strong>de</strong>red films by alternating adsorption of oppositely charged macromolecules. Crystallography Reports, 39(4), 628- 647. Lyngaae-Jorgensen, J., & Utracki, L. A. (2003). Structuring polymer blends with bicontinuous phase morphology. II. Tailoring blends with ultralow critical volume fraction. Polymer, 44(5), 1661-1669. M. Dimitrova, Y. A. P. L. F. M. M. W. C. S. Y. H. J. C. V. J. O. (2007). A<strong>de</strong>noviral Gene Delivery from Multilayered Polyelectrolyte Architectures. Advanced Functional Materials, 17(2), 233-245. 222
Macdiarmid, A. G., Jin-Chih, C., Halpern, M., Wu-Song, H., Shao-Lin, M., Somasiri, L. D., et al. (1985). `Polyaniline': interconversion of metallic and insulating forms. Paper presented at the Proceedings of the International Conference on the Physics and Chemistry of Low-Dimensional Synthetic Metals (ICSM 84), 17-22 June 1984, UK. Malek, G., Johnson, L. V., Mace, B. E., Saloupis, P., Schmechel, D. E., Rickman, D. W., et al. (2005). Apolipoprotein E allele-<strong>de</strong>pen<strong>de</strong>nt pathogenesis: A mo<strong>de</strong>l for age-related retinal <strong>de</strong>generation. Proceedings of the National Aca<strong>de</strong>my of Sciences of the United States of America, 102(33), 11900-11905. Malmonge, L. F., Lopes, G. d. A., Langiano, S. d. C., Malmonge, J. A., Cor<strong>de</strong>iro, J. M. M., & Mattoso, L. H. C. (2006). A new route to obtain PVDF/PANI conducting blends. European Polymer Journal, 42(11), 3108-3113. Man, W., & Shaw, L. (2006). Electrical and mechanical behaviors of carbon nanotube- filled polymer blends. Journal of Applied Polymer Science, 99(2), 477-488. Maoz, R., Frydman, E., Cohen, S. R., & Sagiv, J. (2000). Constructive nanolithography: Site<strong>de</strong>fined silver self-assembly on nanoelectrochemically patterned monolayer templates. Advanced Materials, 12(6), 424-429. Margolis, J. M. (1989). Conductive Polymers and Plastics. New York: Chapman and Hall. Mateescu, E. M., Jeppesen, C., & Pincus, P. (1999). Overcharging of a spherical macroion by an oppositely charged polyelectrolyte. Europhysics Letters, 46(4), 493-498. Mathur, P., Misra, S. C. K., Singh, B. P., & Tripathi, P. (2002). Semiconducting polyaniline nanocrystalline thin films for electronic and sensor applications, Delhi, India. Matos, M., Favis, B. D., & Lomellini, P. (1995). Interfacial modification of polymer blends--the emulsification curve: 1. Influence of molecular weight and chemical composition of the interfacial modifier. Polymer, 36(20), 3899-3907. Mattoso, L. H. C., Leite, F. L., Paterno, L. G., Borato, C. E., Herrmann, P. S. P., & Oliveira, O. N., Jr. (2005). Study on the adsorption of poly(o-ethoxyaniline) nanostructured films using atomic force microscopy. Polymer, 46(26), 12503-12510. McMaster, L. P. (2002). Aspects of Polymer-Polymer Thermodynamics. [doi: 10.1021/ma60035a024]. Macromolecules, 6(5), 760-773. Mekhilef, N., & Verhoogt, H. (1996). Phase inversion and dual-phase continuity in polymer blends: theoretical predictions and experimental results. Polymer, 37(18), 4069-4077. Meli, M.-V., & Lennox, R. B. (2003). Preparation of Nanoscale Au Islands in Patterned Arrays. Langmuir, 19(22), 9097-9100. Metelkin, V. I., & Blekht, V. S. (1984). Formation of a Continuous Phase in Heterogeneous Polymer Mixtures. Colloid Journal of the USSR (English Translation of Kolloidnyi Zhurnal), 46(3), 425-429. Miles, I. S., & Zurek, A. (1988a). Preparation, structure, and properties of two-phase cocontinuous polymer blends. Polymer Engineering & Science, 28(12), 796-805. 223
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© Sepehr Ravati, 2010. UNIVERSITÉ
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DEDICATED To my parents iii
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RÉSUMÉ Cette thèse présente, po
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devenir une structure hiérarchique
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ABSTRACT This thesis presents, for
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system can be increased from 10 -15
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CONDENSÉ EN FRANÇAIS Dans ce trav
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deuxième coquille de PS. Les phase
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structures à percolation multiple
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autre sous-type de morphologie dans
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TABLE OF CONTENTS DEDICATION.......
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xxiii 2.4.1.1.1 Charged Polymer Ads
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5.3.4 Annealing Test ..............
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xxvii REFERENCES ..................
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LIST OF FIGURES xxix Figure 1-1. a)
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Figure 2-12. SEM photomicrograph of
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Figure 2-34. Schematic view of diff
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Figure 4-8. SEM micrographs of vari
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Figure 5-6. a),b) Scanning electron
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and c) triangular concentration dia
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n number of moles p concentration o
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AFM atomic force microscopy LIST OF
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PS-co-PMMA copolymer of PS and PMMA
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1.1 Introduction CHAPTER 1 - INTROD
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Figure 1-2. Human heart, longitudin
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One of the applications for porous
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On the other hand, a novel tri-cont
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2.1 Polymer Blends CHAPTER 2 - LITE
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Based on Sterling’s approximation
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Antonoff’s rule (Equation 2-13) i
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2.1.2.1 Binary Polymer Blends 2.1.2
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Some other studies(Everaert, Aerts,
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where the parameter z is dependent
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“compatibilization” was suggest
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a) λ BC A and B are matrices, b) C
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Reignier & Favis, 2000, 2003a; Reig
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measure the interfacial tension of
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a) b) Figure 2-6. Dependence of the
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Omonov et al. found double percolat
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2.1.2.2.3 Effect of Composition on
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a) b) C B A c) Figure 2-12. SEM pho
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In the case where PS is the matrix,
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Posthuma de Boer, 1999) (Kumin & Ch
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lattice, such as square lattice, wi
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magnetization, which is a function
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Polymers have long been thought of
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epoxy as a function of nanotube wei
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Figure 2-19. Approaching the percol
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Figure 2-21. Transmission electron
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Figure 2-22: Dependence of PE conti
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Figure 2-24. Plot of the total numb
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chain provides the conductive path
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2.3.1.2.1 Polyaniline One of the mo
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CoPA/LLDPE/PANI blend and a poor-qu
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Narkis and co-workers extended and
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Figure 2-31: Conductivity of PVDF/P
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organic thin films, a novel and str
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on the topic have been reported in
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succeeded in creating thin films wi
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Addition of salt to the solution of
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different from that of linear homop
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Figure 2-39. Macromolecule with a)
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polyanion such as hyaluronan (HA)(P
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2.4.1.1.7 Effect of Salt on Multila
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2.4.1.1.8 Overcompensation of the M
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important factors determining the g
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As shown in Figure 2-44, swelling a
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increasing the pH value due to a de
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CHAPTER 3 - ORGANIZATION OF THE ART
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discussed above, HDPE, PS, PMMA, an
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CHAPTER 4 - LOW PERCOLATION THRESHO
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or model which predicts where the p
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concentration threshold for the ons
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chemical and weathering resistance,
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Table 4-1. Material Characteristics
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filled with blend pellets. To facil
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4.3.6 Conductivity Measurements DC
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experimentally in this research gro
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a) b) c) d) Figure 4-4. Schematic i
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microstructure of the quaternary bl
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a) b) c) d) Figure 4-6. SEM microgr
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a) b) PVDF PS PMMA c) d) e) HDPE PS
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Uniform layers of PS and PMMA situa
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the concentration of HDPE is increa
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a) b) c) e) Figure 4-11. SEM microg
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melt-processable and contains 25 wt
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One question that should be address
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Conductivity(S/cm) Ternary Blend 1,
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phase(PMMA), the concentration of P
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(6) Virgilio, N.; Desjardins, P.; L
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ONION MORPHOLOGY HDPE PVDF PS Contr
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work described above has focused on
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thermodynamic explanation to predic
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four-point probe increases continuo
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in the rheology tests were compress
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5.3.6 Layer-by-Layer Deposition The
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prepare a polymer blend structure w
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a) b) c) Figure 5-3. Scanning elect
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spontaneously self-assembled. After
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a) b) c) d) e) f) g) h) Figure 5-5.
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Since the ultra-low surface area va
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c) a) b) Figure 5-6. a),b) Scanning
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salt to a PSS polyelectrolyte solut
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A relationship between macropore si
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close together. It is interesting t
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Figure 5-9. Mass increase (%) indic
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In this work the conductance of the
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deposited PANI layers increases unt
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- Page 219 and 220: 6.2 Introduction It is well-known t
- Page 221 and 222: modified version of Harkins theory(
- Page 223 and 224: 6.3 Experimental 6.3.1 Materials Co
- Page 225 and 226: Complex voscosity (Pa.s) 1,0E+04 1,
- Page 227 and 228: 6.3.5.2 Focused Ion Beam (FIB) and
- Page 229 and 230: a) c) b) d) e) f) PMMA PMMA HDPE HD
- Page 231 and 232: y Harkins theory, PS will always si
- Page 233 and 234: a) b) c) d) e) f) PS Figure 6-6. a)
- Page 235 and 236: a) b) HDPE : black PS : grey PMMA :
- Page 237 and 238: 6.4.6 Continuity, Co-continuity, an
- Page 239 and 240: c) V III II I VII I IV VI Figure 6-
- Page 241 and 242: Continuity Scheme (a) Figure 6-10.
- Page 243 and 244: Addition of a low concentration of
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- Page 249 and 250: Three examples are shown in Figure
- Page 251 and 252: (9) Mekhilef, N.; Verhoogt, H. Poly
- Page 253 and 254: structures are formed due to the co
- Page 255 and 256: CONCLUSION AND RECOMMENDATIONS In t
- Page 257 and 258: REFERENCES A. K. Gupta, K. R. S. (1
- Page 259 and 260: Caruso, F. (2003). Hollow Inorganic
- Page 261 and 262: Domenech, S. C., Bortoluzzi, J. H.,
- Page 263 and 264: Geuskens, G., Gielens, J. L., Geshe
- Page 265 and 266: Hou, S., Harrell, C. C., Trofin, L.
- Page 267: Krass, H., Papastavrou, G., & Kurth
- Page 271 and 272: Niziol, J., & Laska, J. (1999). Con
- Page 273 and 274: Reghu, M., Yoon, C. O., Yang, C. Y.
- Page 275 and 276: Shirakawa, H., Louis, E. L., MacDia
- Page 277 and 278: Utracki, L. A. (1991). On the visco
- Page 279 and 280: Yasuda, K., Armstrong, R., & Cohen,
- Page 281 and 282: literature has examined factors inf
- Page 283 and 284: (Reignier & Favis, 2000, 2003a; Rei
- Page 285 and 286: Table A-1.2. Interfacial tensions a
- Page 287 and 288: acquisition of images with a very h
- Page 289 and 290: Table A-1.3. Continuity of the PMMA
- Page 291 and 292: (17) Reignier, J.; Favis, B. D., Ma
- Page 293 and 294: PANI. Theoretically, the extent of
- Page 295 and 296: Equation A-2.7 0( ) 0 1. 5 σ = σ
- Page 297 and 298: Cumulative Mass × 10 5 (g) dipping
- Page 299 and 300: of PANI, and an increase in the con
- Page 301 and 302: Resistance(ohm) 1.0E+12 1.0E+11 1.0
- Page 303 and 304: esistance value. Samples containing
- Page 305 and 306: The results of resistance for PS/PE
- Page 307 and 308: Caruso, F., & Schuler, C. (2000). E