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DIGEST 2006 - Sabita

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The total analysis of the bitumens<br />

showed that they contained small<br />

amounts of volatile aromatic<br />

hydrocarbons, notably the BETX<br />

compounds and trimethylbenzene<br />

isomers, plus low amounts of<br />

polycyclic aromatic hydrocarbons<br />

(PAHs) such as naphthalene,<br />

anthracene, phenanthrene and<br />

pyrene: none of the PAHs<br />

observed are classified as known<br />

human or animal carcinogens.<br />

provided the estimated<br />

environmental concentration is<br />

less that the acceptable risk limit<br />

of the species, in this case Pb.<br />

Therefore, all the penetration<br />

grade bitumens delisted for<br />

disposal to general waste sites and<br />

can be disposed to medium or<br />

large general waste landfills that<br />

have a leachate management<br />

system, i.e. GMB+ or GLB+.<br />

Traces of chloroform, bromodichloromethane<br />

and phthalate<br />

esters were also detected in some<br />

of the samples. Although these<br />

organic species were identified in<br />

the bitumen samples, only toluene<br />

was detected in the leach solutions<br />

– but at trace levels close to the<br />

detection limit of 1ppb. There are,<br />

therefore, no<br />

organic compounds<br />

leached from the<br />

samples that can<br />

have a significant<br />

impact on the<br />

environment.<br />

Two samples of the<br />

penetration grade<br />

bitumen, B and D,<br />

leached Pb at<br />

concentrations just<br />

above its acceptable<br />

risk limit of 0.10<br />

mg/l and, therefore<br />

formally classify as<br />

high hazard (HG2) wastes in terms<br />

of the Minimum Requirements.<br />

Samples A and C formally<br />

classified as non-hazardous in<br />

terms of the Minimum<br />

Requirements. Even though a<br />

waste formally classifies as<br />

hazardous it can be delisted for<br />

disposal to a general waste landfill<br />

There are no<br />

organic<br />

compounds<br />

leached from<br />

the samples<br />

that can have<br />

a significant<br />

impact on the<br />

environment.<br />

Final report<br />

The final report produced early in<br />

2003 proposed that application be<br />

made to DWAF for approval of the<br />

delisting of penetration grade<br />

bitumens and that this include a<br />

request also for disposal to GBsites<br />

because GB+ landfills are not<br />

available in many<br />

areas within a<br />

reasonable<br />

transport distance.<br />

In their reply<br />

received on the 9th<br />

June 2004 DWAF<br />

gave permission for<br />

bitumen waste to<br />

be considered<br />

delisted subject to<br />

the conditions that<br />

if any uncertainty<br />

exists about<br />

whether a specific<br />

material falls within<br />

the tested parameters, then<br />

further analysis and leachate tests<br />

may be required. The delisted<br />

material may only be disposed of<br />

on a permitted facility, after the<br />

Permit Holder has applied and<br />

received written permission from<br />

DWAF.<br />

127

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