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handbook of carbon, graphite, diamond and fullerenes

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4.5 Mechanical Applications<br />

Molded Graphite 117<br />

Fine-grain, high-density, <strong>and</strong> low-porosity molded <strong>graphite</strong> is extensively<br />

used for bearings <strong>and</strong> seals, particularly in high-temperature applications<br />

(up to 600°C) where conventional liquid lubricants degrade rapidly. It<br />

has excellent lubricating <strong>and</strong> frictional properties (reviewed in Sec. 2.5<br />

above), it is chemically resistant, its high thermal conductivity helps<br />

dissipate the heat generated by rubbing action <strong>and</strong>, at high temperature<br />

(>500°C), its compressive strength is superior to that <strong>of</strong> most other<br />

engineering materials.<br />

However molded <strong>graphite</strong> cannot be used to seal materials that would<br />

attack it chemically, such as aqua regia, perchloric acid, <strong>and</strong> oleum (fuming<br />

sutfuric acid) (see Ch. 3, Sec. 7.0). Sealing failure may also occur with<br />

abrasive materials such as chromic acid, chromic oxide, chrome plating<br />

compounds, potassium dichromate, sodium chromate, <strong>and</strong> sodium dichro-<br />

The following is a partial list <strong>of</strong> current commercial applications <strong>of</strong><br />

bearings <strong>and</strong> seals:<br />

• Seal rings for gas-turbine engines to protect compressorshaft<br />

bearing <strong>and</strong> engine oil system for 600°C gases, at<br />

rubbing speed <strong>of</strong> 150 m/s <strong>and</strong> 10,000 hours service.<br />

• Seal rings in chemical pumps for corrosive-fluid transfer with<br />

a rubbing speed <strong>of</strong> 15 m/s, operating up to 100°C for 10,000<br />

hours.<br />

• Seal rings for water pumps <strong>of</strong> industrial <strong>and</strong> truck diesel<br />

engine, operating at 120°C <strong>and</strong> 0.18 N/mm 2 (25 psi) for20,000<br />

hours.<br />

• Seals rings for automobile freon air compressor for air<br />

conditioning, operating up to 1.75 N/mm 2 (250 psi) <strong>and</strong> 93°C.<br />

• Seal rings for home washing machine <strong>and</strong> dishwasher water<br />

pumps, operating at 0.28 N/mm 2 <strong>and</strong> to 66°C for 10 years<br />

• O-rings for cylinder heads <strong>of</strong> race-car engines<br />

Other mechanical applications <strong>of</strong> molded <strong>graphite</strong> include glass-lehr<br />

roll bearings, roller bearings for jet-engine exhaust nozzles, metering seats<br />

for gasoline pumps, vane pumps for air compressors, rupture disks, <strong>and</strong><br />

many others.

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