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handbook of carbon, graphite, diamond and fullerenes

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xvi Contents<br />

6.0 CERAMIC-MATRIX, CARBON-FIBER COMPOSITES 218<br />

6.1 Matrix Materials <strong>and</strong> Fiber-Matrix Interaction 219<br />

6.2 Applications 220<br />

7.0 OTHER APPLICATIONS OF CARBON FIBERS 222<br />

7.1 High-Temperature Thermal Insulation 222<br />

7.2 Electrical Applications 222<br />

7.3 Electrochemical Applications 222<br />

REFERENCES 223<br />

10 Natural Graphite, Graphite Powders, Particles,<br />

<strong>and</strong> Compounds 226<br />

1.0 NATURAL GRAPHITE 226<br />

1.1 Characteristics <strong>and</strong> Properties 226<br />

1.2 Types <strong>of</strong> Natural Graphite 227<br />

1.3 Occurrence <strong>and</strong> Production 228<br />

1.4 Processing <strong>and</strong> Applications 228<br />

2.0 CARBON-DERIVED POWDERS AND PARTICLES 228<br />

2.1 Carbon Black 229<br />

2.2 Lampblack 230<br />

2.3 Acetylene Black 231<br />

3.0 INTERCALATED COMPOUNDS AND LUBRICATION 232<br />

3.1 Covalent Graphite Compounds 232<br />

3.2 Graphite Intercalation Compounds 236<br />

3.3 Applications 238<br />

4.0 ACTIVATION, ADSORPTION AND CATALYSIS 240<br />

4.1 Charcoal <strong>and</strong> Activation 240<br />

4.2 Adsorption 241<br />

4.3 Catalyst Support 242<br />

REFERENCES 243<br />

11 Structure <strong>and</strong> Properties <strong>of</strong> Diamond <strong>and</strong><br />

Diamond Polytypes 244<br />

1.0 INTRODUCTION 244<br />

2.0 STRUCTURE OF DIAMOND AND DIAMOND POLYTYPES 245<br />

2.1 Analytical Techniques 245<br />

2.2 Atomic Structure <strong>of</strong> Diamond 247<br />

2.3 Crystal Structures <strong>of</strong> Diamond 247<br />

2.4 Diamond Crystal Forms 250<br />

2.5 The Polytypes <strong>of</strong> Diamond 252<br />

3.0 IMPURITIES IN DIAMOND AND CLASSIFICATION 253<br />

3.1 Impurities 253<br />

3.2 Classification <strong>of</strong> Diamonds 256

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