handbook of carbon, graphite, diamond and fullerenes

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Natural and High-Pressure Synthetic Diamond 301 19. McEachron, R. W. and Lorence, S. C, Ceramic Bulletin, 67(6) :1031 - 1036(1988) 20. Subramanian, K., Ceramic Bulletin 67(6) :1026-1029 (1988) 21. Ikawa, N., Shimada, S., and Morooka, H., T, Bull. Japan Soc. ofPrec. Eng., 21(4):233-238 (1987) 22. Schaible, J., Cutting Tool Engineering, 41 (3) :106-109 (June 1989) 23. Diamond Heat Sinks, Technical Brochure from Drukker & Zn. NV, 1001 MC. Amsterdam, The Netherland (1989) 24. Seal, M., Interdisciplinary Science Review, 14(1) :64-76 (1989)
13 CVD Diamond 1.0 INTRODUCTION The production of diamond coatings is now possible by low-pressure vapor-phase synthesis under relatively benign conditions. This development should open the door to the full exploitation of the unique properties of diamond at a cost that is still high but that will likely be reduced as technology improves and production is achieved on an industrial scale. At this time, the technology remains mostly at the laboratory stage and only a few applications are on the market. Yet the future appears promising with a broad range of potential applications in many industrial areas such as heat sinks for electronic devices, advanced semiconductors and tool coatings. The low-pressure vapor-phase process is based on chemical vapor deposition (CVD) and the material is often referred to as "vapor-phase diamond," "diamond coating," or "CVD diamond". "CVD diamond" will be used in this book. Diamond coatings are also produced by physical vapor deposition (PVD). Such coatings however are a mixture of sp 2 (graphite) and sp 3 (diamond) bonds and are considered a different material usually referred to as diamond-like carbon (DLC). They are reviewed in Ch. 14. CVD-diamond coatings are polycrystalline, as opposed to natural and high-pressure synthetic diamond which are normally single crystals. This polycrystalline characteristic has important bearing on the general properties of the coatings as shown in Sec. 4.0. 302
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HANDBOOK OF CARBON, GRAPHITE, DIAMO
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Contents 1 Introduction and General
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xii Contents 5.0 ELECTRICAL PROPERT
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xiv Contents 2.0 THE CVD OF PYROLYT
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xvi Contents 6.0 CERAMIC-MATRIX, CA
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xviii Contents 4.0 NATURAL AND HIGH
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xx Contents 2.0 STRUCTURE OF THE FU
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Preface ix technology, processes, e
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2 Carbon, Graphite, Diamond, and Fu
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10 Carbon, Graphite, Diamond, and F
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Synthetic Carbon and Graphite: Carb
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100 Carbon, Graphite, Diamond, and
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Vitreous Carbon 1.0 GENERAL CONSIDE
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8 Carbon Fibers 1.0 GENERAL CONSIDE
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Applications of Carbon Fibers 1.0 C
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10 Natural Graphite, Graphite Powde
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11 Structure and Properties of Diam
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15 The Fullerene Molecules 1.0 GENE
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Glossary Ablation: The removal of m
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Index Ablation 38 Absorption bands
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Copyright © 1993 by Noyes Publicat
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vi Series HANDBOOK OF CHEMICAL VAPO
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