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handbook of carbon, graphite, diamond and fullerenes

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The Element Carbon 21<br />

loses a proton (going from seven to six), thus decreasing in atomic number<br />

<strong>and</strong> becoming 14 C.<br />

As mentioned above, 14 C is a radioactive isotope <strong>and</strong> decays spontaneously<br />

by emitting p" particles, thus forming a nitrogen atom, as shown<br />

schematically in Fig. 2.3. The processes <strong>of</strong> formation <strong>and</strong> decay are in<br />

equilibrium in the atmosphere <strong>and</strong> the amount <strong>of</strong> 14 C remains essentially<br />

constant at a low level. Much <strong>of</strong> this 14 C is found in the atmospheric <strong>carbon</strong><br />

dioxide.<br />

i 4 Catom<br />

(Parent)<br />

6 Protons<br />

6 Neutrons<br />

6 Electrons<br />

14 N atom<br />

(Daughter)<br />

7 Protons<br />

7 Neutrons<br />

7 Electrons<br />

A neutron <strong>of</strong> the 14 C atom spontaneously forms<br />

a proton <strong>and</strong> a beta particle which becomes the<br />

new electron <strong>of</strong> the nitrogen atom.<br />

Figure 2.3. Decay <strong>of</strong> the 14 C radioactive <strong>carbon</strong> isotope.' 8 '<br />

Carbon-14 in Living <strong>and</strong> Dead Matter. Plants continuously absorb<br />

CO2 <strong>and</strong>, consequently, maintain a constant level <strong>of</strong> 14 C in their tissues.<br />

Animals consume plants (or other plant-eating animals) <strong>and</strong> thus every<br />

living thing contains <strong>carbon</strong> that includes a small amount <strong>of</strong> 14 C in<br />

essentially the same ratio as the 14 C in the atmosphere. This amount is only<br />

1 x 10 8 <strong>of</strong> the amount <strong>of</strong> 12 C.<br />

After death, 14 C is no longer replaced <strong>and</strong>, through the radioactive<br />

decay process, remains in dead matter in a steadily diminishing amount as<br />

time goes by. This amount can be measured (<strong>and</strong> the years since death<br />

readily computed) by counting the number <strong>of</strong> p" particles emitted by the

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