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handbook of carbon, graphite, diamond and fullerenes

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The Fullerene Molecules 361<br />

<strong>and</strong> in the crystal. The G^ is chestnut brown or goldenyellow<br />

<strong>and</strong> the CM is olive-green. The electronic<br />

absorption spectra for these <strong>fullerenes</strong> is shown in Fig.<br />

15.6.f 8 l<br />

As the number <strong>of</strong> <strong>carbon</strong> atoms increases, the s-character<br />

in the Jt-orbital becomes less <strong>and</strong> less pronounced to<br />

become zero in the case <strong>of</strong> the ideal <strong>graphite</strong> crystal,<br />

when the pyramidization angle is zero <strong>and</strong> the number <strong>of</strong><br />

atoms is infinite.<br />

Figure 15.4. Schematic <strong>of</strong> a C60 fullerene molecule.

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