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handbook of carbon, graphite, diamond and fullerenes

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206 Carbon, Graphite, Diamond, <strong>and</strong> Fullerenes<br />

<strong>of</strong> polymer matrix, the processing variables (i.e., temperature, post-cure,<br />

etc.), the ratio <strong>of</strong> fiber to matrix, the type <strong>and</strong> properties <strong>of</strong> the <strong>carbon</strong> fiber,<br />

the orientation <strong>of</strong> the fibers, <strong>and</strong> the fiber architecture in general.<br />

A comprehensive study <strong>of</strong> the effect <strong>of</strong> all these variables on the<br />

properties <strong>of</strong> the composite is a formidable task which has yet to be<br />

undertaken. Yet a good deal <strong>of</strong> information is already available, part <strong>of</strong><br />

which is summarized in the following three tables. The data are compiled<br />

from the literature <strong>and</strong> suppliers' bulletins. Table 9.3 lists the effect <strong>of</strong> the<br />

type <strong>of</strong> <strong>carbon</strong> fiber.<br />

Table 9.3. Effect <strong>of</strong> the Type <strong>of</strong> Carbon Fiber on the Properties<br />

<strong>of</strong> Carbon-Epoxy Composites^ 14 '<br />

Density, g/cm 3<br />

Tensile strength, MPa<br />

Modulus, GPa<br />

Compressive strength, MPa<br />

Shear strength, MPa<br />

Thermal conductivity, W/m-K<br />

T650/42*<br />

1.6<br />

2585<br />

172<br />

1723<br />

124<br />

8.65<br />

Type <strong>of</strong> Fiber<br />

P55**<br />

1.7<br />

896<br />

220<br />

510<br />

55<br />

74<br />

P120***<br />

1.8<br />

1206<br />

517<br />

268<br />

27<br />

398<br />

* T650/42: a high-strength, intermediate-modulus, PAN-based fiber<br />

** P55: an intermediate-modulus, pitch-based fiber<br />

r P120: a high-modulus, pitch based fiber<br />

Notes: 1. The fibers are produced by Amoco Performance Products Inc.<br />

2. The composites have the same epoxy matrix with 62 vol.% fiber.<br />

3. Fiber orientation is unidirectional (0°) <strong>and</strong> tested in the fiber direction.<br />

Particularly noticeable is the high thermal conductivity <strong>of</strong> the graphitized<br />

pitch-based fiber composite which is 46 times that <strong>of</strong> the PAN-based<br />

material.<br />

Table 9.4 shows the effect <strong>of</strong> fiber orientation on the properties. The<br />

large differences in tensile strength <strong>and</strong> modulus <strong>of</strong> unidirectional laminates<br />

tested at 0 <strong>and</strong> 90° should be noted.

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