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Principles of Fluorescence Spectroscopy

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136 TIME-DOMAIN LIFETIME MEASUREMENTS<br />

Table 4.4. F Statistic for Calculation <strong>of</strong> Confidence Intervals a<br />

Probability (P)<br />

Degrees <strong>of</strong> One parameter (p) b<br />

freedom (ν) 0.32 d 0.25 0.10 0.05 0.025 0.01<br />

10 1.09 1.49 3.29 4.96 6.94 10.0<br />

30 1.02 1.38 2.88 4.17 5.57 7.56<br />

60 1.01 1.35 2.79 4.00 5.29 7.08<br />

120 1.00 1.34 2.75 3.92 5.15 6.85<br />

4 1.00 1.32 2.71c 3.84 5.02 6.63<br />

Two Parametersb 10 1.28 1.60 2.92 4.10 5.46 7.56<br />

30 1.18 1.45 2.49 3.32 4.18 5.39<br />

60 1.16 1.42 2.39 3.15 3.93 4.98<br />

120 1.15 1.40 2.35 3.07 3.80 4.79<br />

4 1.14 1.39 2.30 3.00 3.69 4.61<br />

Three Parameters<br />

10 1.33 1.60 2.73 3.71 4.83 6.55<br />

30 1.22 1.44 2.28 2.92 3.59 4.51<br />

60 1.19 1.41 2.18 2.76 3.34 4.13<br />

120 1.18 1.39 2.13 2.68 3.23 3.95<br />

4 1.17 1.37 2.08 2.60 3.12 3.78<br />

Four Parameters<br />

10 1.34 1.59 2.61 3.48 4.47 5.99<br />

30 1.23 1.42 2.14 2.64 3.25 4.02<br />

60 1.20 1.38 2.04 2.53 3.01 3.65<br />

120 1.19 1.37 1.99 2.45 2.89 3.48<br />

4 1.18 1.35 1.94 2.37 2.79 3.32<br />

Five Parameters<br />

10 1.35 1.59 2.52 3.33 4.24 5.64<br />

30 1.23 1.41 2.05 2.53 3.03 3.70<br />

60 1.20 1.37 1.95 2.37 2.79 3.34<br />

120 1.19 1.35 1.90 2.29 2.67 3.17<br />

4 1.17 1.33 1.85 2.21 2.57 3.02<br />

Eight Parameters<br />

10 1.36 1.56 2.34 3.07 3.85 5.06<br />

30 1.22 1.37 1.88 2.27 2.65 3.17<br />

60 1.19 1.32 1.77 2.10 2.41 2.82<br />

120 1.17 1.30 1.72 2.02 2.30 2.66<br />

4 1.16 1.28 1.67 1.94 2.19 2.51<br />

Ten Parameters<br />

10 1.35 1.55 2.32 2.98 3.72 4.85<br />

30 1.22 1.35 1.82 2.16 2.51 2.98<br />

60 1.18 1.30 1.71 1.99 2.27 2.63<br />

120 1.17 1.28 1.65 1.91 2.16 2.47<br />

4 1.15 1.25 1.59 1.83 2.05 2.32<br />

a From [188]. In the ratio <strong>of</strong> χR 2 values, the degrees <strong>of</strong> freedom refer to that for the denominator. The degrees <strong>of</strong> freedom<br />

in the numerator are one, two, or three, for one, two or three additional parameters.<br />

b These values refer to the degrees <strong>of</strong> freedom in the numerator (p).<br />

c This value appears to be incorrect in [188], and was taken from [1].<br />

d The values for 0.32 were calculated with a program (F-stat) provided by Dr. M. L. Johnson, University <strong>of</strong> Virginia.

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