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TO 1-1-700 - Robins Air Force Base

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<strong>TO</strong> 1-1-<strong>700</strong><br />

basic copper sulfate and perhaps hydrated copper carbonate.<br />

The patina in the thin, firmly adhering state actually offers<br />

increased corrosion protection to the base metal, but the patina<br />

in a rough or frosted state should be removed. When coupled<br />

with most metals used in equipment construction, copper is<br />

the less active metal and greatly accelerates corrosion of the<br />

other metals. This is especially true in copper/aluminum couples.<br />

Examples are usually found in electrical components and<br />

in areas where copper bonding strips or wires are fastened to<br />

an aluminum chassis or structural components.<br />

Figure 3-18. Magnesium Corrosion Products<br />

3.8.5 Copper and Copper Alloys. Copper and copper<br />

alloys are quite corrosion resistant and corrosion is usually<br />

limited to staining and tarnish. Generally, such changes in surface<br />

conditions are not dangerous and should ordinarily have<br />

no effect on the part. Copper corrosion is evidenced by the<br />

accumulation of blue or blue-green corrosion products on the<br />

corroded part. Protective paint coatings are seldom required<br />

because of the inherent resistance of the metal. However, paint<br />

finishes may be applied for decorative purposes or if the normal<br />

tarnish or green patina on the copper is objectionable. The<br />

green patina is merely a thin coating consisting mainly of<br />

3.8.6 Cadmium. Metal parts are plated either to increase the<br />

corrosion resistance of the parts or to develop certain physical<br />

properties on the surface of the parts, such as abrasion (wear)<br />

resistance and high temperature oxidation resistance. Parts<br />

may also be plated to create a compatible dissimilar metal<br />

contact, to provide a sacrificial metal layer, or to provide a<br />

satisfactory surface for soldering. Cadmium is used as a coating<br />

to protect steel parts by acting as a sacrificial layer and to<br />

provide a compatible surface when a part is in contact with<br />

other metals such as aluminum alloys. Attack on cadmium is<br />

evidenced by brown to black mottling of the surface or as<br />

white powdery corrosion products. When cadmium shows<br />

mottling and isolated voids or cracks in the coating, the plating<br />

is still performing its protective function. The cadmium plate<br />

on iron or steel continues to protect until such time as actual<br />

iron rust appears (see Figure 3-21). Even then, any mechanical<br />

removal of corrosion products should be limited to metal surfaces<br />

where cadmium has been depleted.<br />

Figure 3-19. Steel Corrosion Products (Rust)<br />

3-13

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