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Untitled - Aerobib - Universidad Politécnica de Madrid

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124 CHAPTER 5. STRUCTURE OF THE COMBUSTION WAVES<br />

to D could only be attained through an endothermic reaction, and this kind of reaction<br />

is impossible in a combustion process. As a consequence, the non-existence of the<br />

strong <strong>de</strong>flagrations is conclu<strong>de</strong>d.<br />

D<br />

v<br />

C<br />

B<br />

P<br />

ε<br />

Figure 5.5: Schematic diagram showing the variation of the velocity of gases in a <strong>de</strong>flagration.<br />

On the other hand, since for a weak <strong>de</strong>flagration the final velocity is subsonic,<br />

nothing is opposed to its existence.<br />

In the weak <strong>de</strong>flagrations diffusion and heat conduction are important and the<br />

system to be used is system B. Diffusion and heat conduction are responsible for<br />

the propagation of the combustion to the unburnt gases, activating their reaction by<br />

diffusion of the active centers (atoms, radicals, etc.) and by heating. As they heat, the<br />

gases expand and accelerate, producing a slight pressure drop throughout the wave.<br />

Fig. 5.6 shows qualitatively the structure of a <strong>de</strong>flagration wave bringing forth, by<br />

comparison with Fig. 5.3, the difference in the mechanism that propagate the process<br />

in each case. The system B of differential equations that must be integrated in or<strong>de</strong>r<br />

to obtain the structure of the <strong>de</strong>flagration wave can be simplified by eliminating x, as<br />

done in §4. Thus obtaining<br />

p Dw<br />

R m T m 2<br />

dY<br />

dε<br />

= Y − ε, (5.49)<br />

λw dT<br />

m 2 dε = c pT − qε + e. (5.50)<br />

In the <strong>de</strong>duction of this system, the state equation p = ρR m T has been used in or<strong>de</strong>r<br />

to eliminate the <strong>de</strong>nsity from the diffusion equation.

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