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MRCSP Phase I Geologic Characterization Report - Midwest ...

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100 CHARACTERIZATION OF GEOLOGIC SEQUESTRATION OPPORTUNITIES IN THE <strong>MRCSP</strong> REGION<br />

studies on the reservoir aspects of the reefs (for examples, see Gill<br />

and others, 1974; Gill, 1977; Sears and Lucia, 1979, 1980).<br />

NATURE OF LOWER AND UPPER CONTACTS<br />

The lower contact of the Niagara Group is gradational with the<br />

underlying Manistique Group (Figure 5). The Salina Group, a<br />

mixed interval of intercalated carbonates and evaporites overlies the<br />

Niagara Group and provides a regional seal that is highly competent<br />

(Figure A8-2). In the lower portion of the Salina Group, the A-1<br />

evaporite formation overlies the inter-reef Niagara but not the pinnacle<br />

reefs. The A-1 carbonate, A-2 evaporite and the A-2 carbonate<br />

and B salt all overlie both the inter-reef and the pinnacle reefs (Sears<br />

and Lucia, 1979).<br />

LITHOLOGY<br />

The reservoir facies consist primarily of porous and permeable<br />

dolostone, although locally primary limestone has reservoir grade porosity<br />

and permeability. Porosity is best developed in the pinnacle reef<br />

core as well as the immediate off-reef facies (fore-reef, flanking beds)<br />

and is characterized primarily by intercrystalline and vuggy pores.<br />

DISCUSSION OF DEPTH AND THICKNESS RANGES<br />

The pinnacle reefs range from 2,000 feet to more than 6,000<br />

feet deep in the Michigan basin (Figure A9-1), with the majority<br />

of reefs at depths that average approximately 3,500 to 4,500 feet.<br />

Reservoir thickness may be highly variable and ranges from a few<br />

feet to several hundred feet. An isopach map was not created for the<br />

<strong>MRCSP</strong> <strong>Phase</strong> I project due to the small, high-relief reef features<br />

that would not have been adequately illustrated by contours generated<br />

by conventional gridding algorithims at the regional scale of<br />

<strong>MRCSP</strong> mapping.<br />

DEPOSITIONAL ENVIRONMENTS/<br />

PALEOGEOGRAPHY/TECTONISM<br />

The pinnacle reefs are located along a carbonate ramp generally<br />

basinward of a shelf edge barrier reef complex. The reefs are characterized<br />

by a complex interaction of biogenic growth and physicochemical<br />

precipitation of carbonate cements. Common reef-builders<br />

include various forms of stromatoporoids and corals indicative of<br />

normal marine conditions during time of deposition. The reefs and<br />

associated facies are generally subdivided into six readily recognizable<br />

sub-facies (Gill, 1977): 1) biohermal mudmound consisting of<br />

carbonate muds and skeletal components including crinoids and<br />

bryozoans; 2) reef core consisting of a massive framework formed<br />

by stromatoporoids, corals, algae, and a variety of subordinate biotic<br />

elements combined with early submarine cements; 3) reef detritus<br />

made up of detrital fragments of the reef core and deposited along<br />

the flanks of the reef; 4) an inter-reef facies comprised of platform<br />

carbonates; 5) restricted (lagoonal) facies consisting of laminated<br />

and bioturbated, peloidal mudstones, and wackestones; and 6)<br />

supratidal/island facies consisting of algal laminated sediments and<br />

other features of high intertidal to supratidal deposition.<br />

The pinnacle reefs were deposited in a tropical to subtropical latitudinal<br />

belt. Subsequent diagenetic dolomitization has been attributed<br />

to a number of mechanisms, including mixing zone processes,<br />

Kohout convection, hypersaline reflux of brines, evaporative drawdown,<br />

and hydrothermal circulation, although most workers agree<br />

that reflux and hydrothermal processes were probably the main<br />

mechanisms (Sears and Lucia, 1980). The relationship between<br />

basin subsidence and eustatic changes at the time of pinnacle reef<br />

deposition is presently unclear; there are a number of studies investigating<br />

the relative timing of reef growth in response to relative sea<br />

level changes.<br />

SUITABILITY AS A CO 2<br />

INJECTION TARGET OR SEAL UNIT<br />

Niagaran reefs have been prolific oil-and-gas-producers After<br />

their productive life, many are converted to gas storage units due<br />

to their high porosity and permeability characteristics and effective<br />

overlying seals. Despite the fact that reservoir-grade rock is<br />

not regionally continuous, but is found in more localized reefs and<br />

reef complexes, the Niagaran reefs should be considered high-quality<br />

targets where CO 2 can be economically transported to the reef<br />

trends. Porosity values can exceed 35 percent locally but typically<br />

average 8 to 12 percent with the best porosity associated with dolomitized<br />

reef cores and flank facies. The best reservoir rocks are<br />

characterized by well-developed intercrystalline and vuggy porosity<br />

with average permeability values of 3 to 10 md. Permeability<br />

can be significantly higher where fractures intersect matrix porosity.<br />

A high-quality sealing unit is provided by the overlying Salina<br />

Group, characterized by abundant salt and anhydrite intercalated<br />

with relatively thin carbonates. Cumulative oil production through<br />

2004 was 336 million barrels of oil (MMbo) and 2.5 trillion cubic<br />

feet (Tcf) of gas, indicating the high-quality porosity and permeability<br />

available in many reefs. While individual reefs and reef<br />

complexes are localized (averaging 50 to 400 acres), they can reach<br />

up to 2,000 acres in size and have from 150 to 700 feet of vertical<br />

relief . Also, the individual reefs are clustered close together within<br />

trends. Thus, once a pipeline is brought to the trend, CO 2 injection<br />

(and enhanced oil recovery) can proceed from reef-to-reef fairly<br />

inexpensively.<br />

A number of the Niagaran reefs are used for natural gas storage<br />

operations in Michigan (Table A9-1). Such operations illustrate the<br />

integrity of the reservoirs for storage operations. The relatively<br />

small surface footprint of the reef-sand thick reservoir with large<br />

capability for storage allow relatively large volumes of gas to be<br />

cycled with few injection and withdrawal wells.<br />

There is currently a project underway to utilize CO 2 from a gasprocessing<br />

plant for enhanced oil recovery from three pinnacle<br />

reefs along the northern Michigan trend. This work is being performed<br />

with the sole purpose of oil recovery in mind, not optimal<br />

sequestration of CO 2. The existence of the pipeline infrastructure<br />

makes this area a highly attractive prospect for pilot sequestration<br />

studies. Such a study would be favorable from logistical,<br />

geotechnical, and economic standpoints, as much is known or can<br />

be established using available data on reservoir heterogeneity and<br />

compartmentalization.

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