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MRCSP Phase I Geologic Characterization Report - Midwest ...

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22 CHARACTERIZATION OF GEOLOGIC SEQUESTRATION OPPORTUNITIES IN THE <strong>MRCSP</strong> REGION<br />

industrial-waste injection well, 2) Class II—brine injection well,<br />

and 3) Class III—solution mining well. Locating all of these wells<br />

had never been accomplished before by all of the <strong>MRCSP</strong> project<br />

members; this information is usually kept by state or federal regulatory<br />

agencies. However, information about these wells, especially<br />

the Class I and II wells (Figure 13) will be crucial in understanding<br />

the injection characteristics of many of the target formations under<br />

consideration. Therefore, under <strong>Phase</strong> II of the <strong>MRCSP</strong> Partnership,<br />

the geologic team will obtain as much information as possible from<br />

these injection operations.<br />

Salinity Grid<br />

A salinity grid can be generated from mapping, either by direct<br />

interpolation (Kriging etc.) or by exploiting the general relationship<br />

of salinity increasing with depth. Mapping salinity accurately<br />

in this region is difficult because the data needed are not routinely<br />

gathered and submitted to state agencies; therefore the coverage is<br />

sparse. For example, the Mount Simon Sandstone has only 18 measurements<br />

of salinity scattered across the <strong>MRCSP</strong> area. In addition,<br />

formation waters are continuously modified by filtration through<br />

clay membranes, ion exchange reactions, precipitation of minerals,<br />

and by the solutioning of the surrounding rocks (Blatt and others,<br />

1980), causing further uncertainty. For these reasons, a statistical<br />

salinity verses depth model was used to create the salinity grids<br />

used in capacity calculations for this investigation. The model was<br />

constructed from existing sample data using least-squares regression.<br />

Individual models were created for each formation and used<br />

with the overburden (depth) maps to make a continuous salinity<br />

grid for each formation.<br />

Geothermal Gradient and Temperature<br />

Models of the surface temperature and geothermal gradient were<br />

created to calculate the temperature at depth for use in the capacity<br />

calculations. For the surface temperature, the thirty-year average<br />

for over 275 cities was obtained for the conterminous United States<br />

(NOAA, 2000). The temperatures were interpolated into a grid using<br />

a minimum curvature algorithm.<br />

For the geothermal gradient, a number of datasets were investigated.<br />

These datasets included the American Association of<br />

Petroleum Geologists (AAPG) bottom-hole temperature dataset<br />

(AAPG, 1994), the Southern Methodist University (SMU) dataset<br />

(Blackwell and Richards, 2004a), and the 2004 AAPG heat flow<br />

dataset (Blackwell and Richards, 2004b). Each dataset was evaluated<br />

for data quality and spatial distribution. The AAPG heat flow<br />

dataset (Blackwell and Richards, 2004b) was not used because the<br />

data distribution was considered too sparse in the project area—only<br />

three heat flow measurements were for Ohio. The 1994 AAPG geothermal<br />

dataset was unsatisfactory because it was uncorrected for<br />

thermal equilibrium and, when analyzed using spatial statistics, the<br />

spatial variance was quite large. Of those evaluated, the SMU dataset<br />

(Blackwell and Richards, 2004a) was the best for this project because<br />

it combined a good combination of data coverage and quality.<br />

A regional correction was applied, which significantly reduced the<br />

spatial variance. In areas where the SMU dataset was missing data,<br />

such as Pennsylvania, data from the AAPG bottom hole temperature<br />

dataset (AAPG, 1994) was used to augment the SMU dataset. The<br />

augmented SMU dataset was used to create the geothermal gradient<br />

grid for the region using kriging in Geostatistical Analyst.<br />

Screening Maps<br />

The large number of maps, data grids, and calculations generated in<br />

this regional assessment make it difficult for the public, or any other<br />

user, to interpret the various attributes related to CO 2 sequestration<br />

in geologic units in the <strong>MRCSP</strong> study area.. Therefore, the geologic<br />

team has devising several methods to condense the various types of<br />

information contained herein into a smaller number of summary maps<br />

for quick reference, by both technical and non-technical audiences.<br />

Several techniques for creating summary maps were investigated.<br />

Approaches ranging from complex expert systems models, which<br />

codify qualitative geological knowledge numerical algorithms, to<br />

simple screening maps. Because the expert systems models rely<br />

on so much soft information (knowledge rather than data), it was<br />

decided, at this stage in the project, that simple Boolean screening<br />

maps were the best approach to presenting meaningful summaries.<br />

Quantifying geologic knowledge through expert systems approaches<br />

must be done with care and can be time consuming if realistic<br />

algorithms are to be developed. Research into more advanced techniques<br />

will continue in <strong>Phase</strong> II.<br />

A screening/planning map was produced using grids for all deep<br />

saline formations. Structure and isopach grids were reclassified into<br />

binary grids showing where the geology was appropriate and inappropriate<br />

for CO 2 injection, then reclassified to show areas where<br />

overburden thickness was greater than 3,000 feet (using the 2,500-<br />

foot rule of thumb for miscible injection, with 500 feet added to<br />

account for potential map error). Isopach grids were reclassified to<br />

show thicknesses greater than 50 feet. The reclassified grids were<br />

recombined into a single grid showing the number of appropriate<br />

targets and the name of the targets (Figure 14). This map can<br />

also be viewed as a 3-dimensional scene (Figure 15). The map is<br />

presented herein and will be discussed further with various stakeholder<br />

groups, including the partnership sponsors, to elicit input on<br />

its usefulness, clarity, and how it can be improved and added-to for<br />

development in <strong>Phase</strong> II.<br />

DATA STORAGE AND DISTRIBUTION<br />

<strong>Geologic</strong> data for this project is provided in both digital and as<br />

hard copy (paper) map formats. This was done to ensure that the<br />

needs of a wide range of stakeholders were met. The approach<br />

allows information to be distributed to individuals ranging from<br />

sophisticated GIS modelers to non-technical users who just need a<br />

map for a planning meeting.<br />

Data Storage<br />

All GIS data is being stored in a centralized ArcSDE database<br />

maintained by the Ohio Division of <strong>Geologic</strong>al Survey. For geologic<br />

target and confining layers, there are contour and grid data,<br />

geologic unit crop lines, and fault locations stored. Point data used<br />

in mapping are stored as a database containing all formation tops<br />

with a listing of basic well-header data (i.e., well operator, location,<br />

producing formation, well status, etc.). The database also contains<br />

all GIS layers created in this project, including layers from the terrestrial<br />

studies, CO 2 sources, surface digital-elevation model, oil<br />

and gas fields, and the various data and grids needed for capacity<br />

calculations. The database may be queried to obtain data for an<br />

individual geologic layer, by formation, depth, location, or any<br />

combination the user requires.

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