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MRCSP Phase I Geologic Characterization Report - Midwest ...

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52 CHARACTERIZATION OF GEOLOGIC SEQUESTRATION OPPORTUNITIES IN THE <strong>MRCSP</strong> REGION<br />

One of the most striking features in the Appalachian basin east<br />

and south of Ohio is the Rome trough (Figures and A1-2). The<br />

Rome trough is a graben that extends from the Lexington fault system<br />

in central Kentucky to at least as far northward as southwestern<br />

Pennsylvania (Woodward, 1961; McGuire and Howell, 1963; Harris<br />

1975; Wagner, 1976; Cardwell, 1977; Beardsley and Cable, 1983;<br />

Shumaker, 1986, 1996; Harper, 1989; Drahovzal and Noger, 1995;<br />

Gao and others, 2000; Wilson, 2000; Harris and others, 2004). The<br />

trough is the result of a Cambrian rifting event that down-dropped<br />

basement rocks thousands of feet. The apparent highly faulted nature<br />

of the Rome trough in eastern Kentucky is interpreted from the<br />

mapped surface geology and a relatively large number of basement<br />

tests that have been integrated with available seismic data (Drahovzal<br />

and Noger, 1995). Farther northeastward, in West Virginia<br />

and Pennsylvania, where the basin is deeper, there are fewer basement<br />

wells and less publicly available seismic data, making these<br />

areas appear to be less faulted. In eastern Kentucky, the structural<br />

relief on the top of the Precambrian is greater than 13,000 feet from<br />

the northern boundary of the Rome trough along the Kentucky<br />

River fault system to the trough’s deepest part near the center of<br />

the graben on the West Virginia state line. The trough in Kentucky<br />

steps down from a high northern boundary fault across a series of<br />

down-to-south normal faults into the center of the graben and then<br />

up again across a lower southern shoulder bounded by a smaller<br />

displacement fault, the Rockcastle River fault. The Rockcastle<br />

River fault changes from a low-displacement normal fault to a highdisplacement<br />

thrust fault in southern Kentucky where it was reactivated<br />

during the Alleghany orogeny (Drahovzal and Noger, 1995;<br />

Drahovzal and White, 2002). Many of the faults of the Rome trough<br />

were reactivated during subsequent Paleozoic orogenic movements<br />

and are expressed in Quaternary-age surface materials.<br />

The relatively symmetrical graben structure of the Rome trough,<br />

as mapped in Kentucky, changes near the West Virginia line to an<br />

asymmetric half graben, dipping southeast and bounded on the<br />

southeast by the major East-Margin fault (Gao and others, 2000;<br />

Wilson, 2000). Offsets along the East-Margin fault are up to 7,000<br />

feet. The half-graben structural character continues north into southwestern<br />

Pennsylvania to the cross-strike structural discontinuity referred<br />

to as the Pittsburgh-Washington lineament (Lavin and others,<br />

1982; Parrish and Lavin, 1982; Alexander and others, in press).<br />

North of the lineament, the structural character of the basement<br />

changes to a southeast dipping monocline cut by down-to-southeast<br />

dipping normal faults. Offsets across the lineament range from 0 to<br />

2,500 feet. Offsets along the down-to-southeast normal faults are<br />

generally less than 500 feet. Several other northwest-oriented lineaments<br />

cross the basement monocline farther to the northeast but<br />

exhibit relatively small offsets. The presence of the Rome trough<br />

north of this lineament is equivocal, but it has been postulated by a<br />

number of workers (Harris, 1975; Wagner, 1976; Shumaker, 1986,<br />

1996; Harper, 1989; Jacobi and others, 2004) to extend into New<br />

York in the north-central part of the state.<br />

The basement rocks of the <strong>MRCSP</strong> study area are extremely important<br />

because of their influence on the overlying Paleozoic rocks.<br />

Basement structure, in particular, has influenced the subsequent<br />

structural history of the Paleozoic rocks. In many cases, major basement<br />

faults were reactivated by later orogenic movement to fault<br />

the younger overlying rocks. Other basement faults show little or no<br />

reactivation and exhibit no shallow expression in Paleozoic rocks.<br />

Still other faults in Paleozoic rocks apparently have no basement<br />

roots, being solely the result of shallow tectonics. Careful study is<br />

required when assessing the faulting in a region to distinguish these<br />

three types of faults. The distinction between the types of faults and<br />

related structures is critical in the siting of sequestration targets in<br />

order to assure the integrity of seals associated with potential CO 2<br />

reservoirs. However, it is known that not all faults are permeable,<br />

or represent points of leakage, because mineralization may seal the<br />

faults, making them impermeable barriers rather than fluid pathways.<br />

Thus, site-specific investigations and testing are required to<br />

ascertain the integrity of any proposed CO 2-storage site.<br />

During <strong>Phase</strong> II of the Regional Carbon Sequestration Partnership<br />

studies, additional data on the basement structures will be<br />

required for those areas that are being considered for CO 2 injection.<br />

Reflection seismic profiles will be required to provide information<br />

on structure, especially faults that could compromise the reservoir<br />

seals. The data may also provide an indication of subsurface lithology,<br />

facies/permeability changes, and may even reveal some<br />

permeable basement zones, which may themselves be candidates<br />

for sequestration. Such initial seismic data will be critical in determining<br />

whether further examination of the area is warranted based<br />

on basement faulting and structure, as well as the structure of shallower<br />

Paleozoic sequestration target zones. Seismic reflection data<br />

will also act as a guide to the location of any subsequent drill holes,<br />

indicating best placement for injection, or where to drill to provide<br />

the most useful analytical information. Subsequent drill-hole and<br />

core data will not only provide critical information on reservoir and<br />

seal properties in the target sequestration zones, but will provide<br />

important basement lithologic and structural data that may have<br />

bearing and influence on overlying reservoirs.<br />

2. CAMBRIAN BASAL SANDSTONES<br />

The basal sandstone interval includes some of the most promising<br />

targets for CO 2 sequestration within the <strong>MRCSP</strong> study area. The<br />

Mt. Simon Sandstone, which is part of this mapped interval, has the<br />

largest sequestration potential of any individual geologic unit within<br />

the <strong>MRCSP</strong> study area (see volume calculations section). However,<br />

the Mt. Simon has also been one of the most misunderstood geologic<br />

units within the region. Many previous workers have assumed<br />

the Mt. Simon was present across much of the region (Janssens,<br />

1973; Havorka and others, 2000; Gupta, 1993) when, in fact, recent<br />

research has shown that the true Mt. Simon pinches out in central<br />

Ohio (Baranoski, in preparation). East of this pinch-out, thinner, less<br />

continuous sandstones are found in this “basal sand” position. Thus,<br />

for the <strong>Phase</strong> I <strong>MRCSP</strong> assessment, these sandstone intervals have<br />

been mapped as one group across the entire region.<br />

Cambrian stratigraphic nomenclature for the <strong>MRCSP</strong> study area<br />

is problematic. A cursory examination of the geologic correlation<br />

chart (Figure 5) demonstrates a lack of regional consistency in<br />

currently accepted geologic terms as well as a number of states<br />

simply using the term “basal sandstone.” In general, this problem<br />

grew from the practice of taking geologic contacts and formalized<br />

terms from outcrops studied in the upper Mississippi Valley and Appalachian<br />

fold and thrust belt and carrying them many miles into the<br />

deep subsurface of the region by analyzing drilling cuttings from<br />

sparse well control and interpreting correlative surfaces. The advent<br />

of modern geophysical logs allowed more detailed regional correlations;<br />

however, geologic terms remain entrenched provincially,<br />

and numerous correlation difficulties are not resolved. While the<br />

same can be said for many younger geologic units, the problem is<br />

especially acute within the deep Cambrian strata because of the low<br />

number of wells, and great distances between wells, that have been

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