22 CHARACTERIZATION OF GEOLOGIC SEQUESTRATION OPPORTUNITIES IN THE <strong>MRCSP</strong> REGION industrial-waste injection well, 2) Class II—brine injection well, and 3) Class III—solution mining well. Locating all of these wells had never been accomplished before by all of the <strong>MRCSP</strong> project members; this information is usually kept by state or federal regulatory agencies. However, information about these wells, especially the Class I and II wells (Figure 13) will be crucial in understanding the injection characteristics of many of the target formations under consideration. Therefore, under <strong>Phase</strong> II of the <strong>MRCSP</strong> Partnership, the geologic team will obtain as much information as possible from these injection operations. Salinity Grid A salinity grid can be generated from mapping, either by direct interpolation (Kriging etc.) or by exploiting the general relationship of salinity increasing with depth. Mapping salinity accurately in this region is difficult because the data needed are not routinely gathered and submitted to state agencies; therefore the coverage is sparse. For example, the Mount Simon Sandstone has only 18 measurements of salinity scattered across the <strong>MRCSP</strong> area. In addition, formation waters are continuously modified by filtration through clay membranes, ion exchange reactions, precipitation of minerals, and by the solutioning of the surrounding rocks (Blatt and others, 1980), causing further uncertainty. For these reasons, a statistical salinity verses depth model was used to create the salinity grids used in capacity calculations for this investigation. The model was constructed from existing sample data using least-squares regression. Individual models were created for each formation and used with the overburden (depth) maps to make a continuous salinity grid for each formation. Geothermal Gradient and Temperature Models of the surface temperature and geothermal gradient were created to calculate the temperature at depth for use in the capacity calculations. For the surface temperature, the thirty-year average for over 275 cities was obtained for the conterminous United States (NOAA, 2000). The temperatures were interpolated into a grid using a minimum curvature algorithm. For the geothermal gradient, a number of datasets were investigated. These datasets included the American Association of Petroleum Geologists (AAPG) bottom-hole temperature dataset (AAPG, 1994), the Southern Methodist University (SMU) dataset (Blackwell and Richards, 2004a), and the 2004 AAPG heat flow dataset (Blackwell and Richards, 2004b). Each dataset was evaluated for data quality and spatial distribution. The AAPG heat flow dataset (Blackwell and Richards, 2004b) was not used because the data distribution was considered too sparse in the project area—only three heat flow measurements were for Ohio. The 1994 AAPG geothermal dataset was unsatisfactory because it was uncorrected for thermal equilibrium and, when analyzed using spatial statistics, the spatial variance was quite large. Of those evaluated, the SMU dataset (Blackwell and Richards, 2004a) was the best for this project because it combined a good combination of data coverage and quality. A regional correction was applied, which significantly reduced the spatial variance. In areas where the SMU dataset was missing data, such as Pennsylvania, data from the AAPG bottom hole temperature dataset (AAPG, 1994) was used to augment the SMU dataset. The augmented SMU dataset was used to create the geothermal gradient grid for the region using kriging in Geostatistical Analyst. Screening Maps The large number of maps, data grids, and calculations generated in this regional assessment make it difficult for the public, or any other user, to interpret the various attributes related to CO 2 sequestration in geologic units in the <strong>MRCSP</strong> study area.. Therefore, the geologic team has devising several methods to condense the various types of information contained herein into a smaller number of summary maps for quick reference, by both technical and non-technical audiences. Several techniques for creating summary maps were investigated. Approaches ranging from complex expert systems models, which codify qualitative geological knowledge numerical algorithms, to simple screening maps. Because the expert systems models rely on so much soft information (knowledge rather than data), it was decided, at this stage in the project, that simple Boolean screening maps were the best approach to presenting meaningful summaries. Quantifying geologic knowledge through expert systems approaches must be done with care and can be time consuming if realistic algorithms are to be developed. Research into more advanced techniques will continue in <strong>Phase</strong> II. A screening/planning map was produced using grids for all deep saline formations. Structure and isopach grids were reclassified into binary grids showing where the geology was appropriate and inappropriate for CO 2 injection, then reclassified to show areas where overburden thickness was greater than 3,000 feet (using the 2,500- foot rule of thumb for miscible injection, with 500 feet added to account for potential map error). Isopach grids were reclassified to show thicknesses greater than 50 feet. The reclassified grids were recombined into a single grid showing the number of appropriate targets and the name of the targets (Figure 14). This map can also be viewed as a 3-dimensional scene (Figure 15). The map is presented herein and will be discussed further with various stakeholder groups, including the partnership sponsors, to elicit input on its usefulness, clarity, and how it can be improved and added-to for development in <strong>Phase</strong> II. DATA STORAGE AND DISTRIBUTION <strong>Geologic</strong> data for this project is provided in both digital and as hard copy (paper) map formats. This was done to ensure that the needs of a wide range of stakeholders were met. The approach allows information to be distributed to individuals ranging from sophisticated GIS modelers to non-technical users who just need a map for a planning meeting. Data Storage All GIS data is being stored in a centralized ArcSDE database maintained by the Ohio Division of <strong>Geologic</strong>al Survey. For geologic target and confining layers, there are contour and grid data, geologic unit crop lines, and fault locations stored. Point data used in mapping are stored as a database containing all formation tops with a listing of basic well-header data (i.e., well operator, location, producing formation, well status, etc.). The database also contains all GIS layers created in this project, including layers from the terrestrial studies, CO 2 sources, surface digital-elevation model, oil and gas fields, and the various data and grids needed for capacity calculations. The database may be queried to obtain data for an individual geologic layer, by formation, depth, location, or any combination the user requires.
GEOLOGIC MAPPING PROCEDURES, DATA SOURCES AND METHODOLOGY 23 EXPLANATION Injection Wells Class I Class II P R O J E C T L I M I T 50 25 0 50 100 Miles 50 25 0 50 100 150 Kilometers ³ Figure 13.—Locations of Class I (hazardous and industrial waste) and Class II (oil field brine) injection wells.
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