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MRCSP Phase I Geologic Characterization Report - Midwest ...

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INTRODUCTION TO THE <strong>MRCSP</strong> REGION’S GEOGRAPHY AND GEOLOGY<br />

9<br />

GEOLOGIC UNCERTAINTIES<br />

Our knowledge about the sequestration potential in deep geologic<br />

units is limited by the availability of data on the various subsurface<br />

attributes of the region. For example, in making broad regional assessments,<br />

such as this <strong>Phase</strong> I task, our assessment is constrained,<br />

and thus limited, by the availability of oil-and-gas-well data, accessibility<br />

to seismic data, and our previous experience and working<br />

knowledge in and of the region.<br />

In general, the amount of data available for mapping and analysis<br />

of any particular unit is directly proportional to its depth below the<br />

surface. Thus, the deeper the unit, the less certain is our understanding<br />

of the various parameters related to, and needed for, assessing<br />

geologic CO 2 sequestration targets in the subsurface of the <strong>MRCSP</strong><br />

region. Unfortunately, since our primary data set is based mainly<br />

on oil and gas wells, the control points used to map the various<br />

units discussed herein is limited by where and how deep companies<br />

in this industry drill. The deeper the well, the more costly it is to<br />

drill; hence, overall, there are fewer deep wells. This is especially<br />

true once the well depth exceeds about 6,000 to 7,000 feet. Consequently,<br />

our knowledge on the deepest portions of the region is<br />

limited—to date, no wells are known to have been drilled to the<br />

deepest extreme of the Appalachian basin, a depth thought to exceed<br />

45,000 feet. These depths are not practical, in any event, for current<br />

sequestration consideration.<br />

Another deep feature of the region that may represent a significant<br />

potential sequestration target is the region containing the Rome<br />

trough, a inadequately known structural feature in the subsurface of<br />

the Appalachian basin (Figure 6). The Rome trough is a large, deep<br />

feature that occurs in Kentucky, West Virginia, and Pennsylvania<br />

and is approximately parallel to the Ohio River (it is thought the<br />

current location of sections of the Ohio River are controlled by<br />

structural irregularities related to this feature). Seismic data and a<br />

limited number of deep wells drilled in this area indicate the Lower<br />

Paleozoic geologic section rapidly expands within this feature. For<br />

example, it is known that several thousand feet of sedimentary rock<br />

occur in the Rome trough proper, that are not known to exist outside<br />

the boundaries of the feature. These same data indicate sandstones,<br />

some of which may have good storage reservoir potential, occupy<br />

many portions of this expanded section. However, what is not<br />

known is how extensive these potential reservoirs are. Nonetheless,<br />

some of these potential sandstone sequestration targets are within<br />

the economic limit of feasibility making them a possible target for<br />

consideration as a large injection target (perhaps in the 9,000 to<br />

12,000-foot range).<br />

It is beyond the scope or economic abilities of this project to test<br />

these deep regions. However, their presences should be mentioned<br />

because, should the Rome trough contains the sandstone intervals<br />

that some believe to be there, this deep feature could easily double<br />

the sequestration potential within the <strong>MRCSP</strong> region.<br />

STRATIGRAPHIC CORRELATION<br />

Assessing the regional potential for CO 2 sequestration requires<br />

an understanding of the many stratigraphic units (groups and formations)<br />

in the <strong>MRCSP</strong> region and their geologic and stratigraphic<br />

relationships between various areas of the partnership (Figure 5).<br />

Therefore, a regional correlation chart was one of the first, and most<br />

significant, undertakings accomplished by the geologic team.<br />

Each state has, over the past 150 years or so, developed its own<br />

stratigraphic nomenclature in order to explain the geologic history<br />

and stratigraphic succession of rocks within each state—some of<br />

these terms are unique to rocks that occur only in the subsurface.<br />

The changing geologic character of many of these rock units, or at<br />

least their position within a geologic basin, has created some differences<br />

in the nomenclatures used in each state (see Figure 5). Other<br />

variations between states are related to different methods used for<br />

establishing the placement of unit boundaries or how a unit is classified<br />

(ranked, i.e., group, formation, member) within a specific rock<br />

interval or in a different area of the region. Prior to the development<br />

of this correlation chart, no detailed chart showing the correlations<br />

between the individual <strong>MRCSP</strong> states existed. We continue to refine<br />

this chart as work progresses. More detailed correlation charts,<br />

where needed, are presented in the discussion of the individual<br />

units/intervals in Appendix A.<br />

SELECTION OF MAPPED UNITS AND LIMITATIONS<br />

Using the regional correlation chart and our knowledge of these<br />

units as a basis, an initial list of potential CO 2 sequestration reservoirs<br />

and seal (cap rock) intervals was chosen for further consideration.<br />

Known stratigraphic intervals of saline formations, petroleum-producing<br />

units, gas-generating (source rock) carbonaceous<br />

shales, and coal-bearing units were identified in each state. Many<br />

of these intervals can be readily correlated between states or basins;<br />

however, others are restricted to a single basin or regions with a<br />

basin, and determining their relationship to other more established<br />

units is problematic.<br />

<strong>Phase</strong> I of all DOE regional partnership projects called for a regional<br />

assessment of the CO 2 sequestration potential in each partnership<br />

area within a defined time frame. To expedite our evaluations,<br />

a list was developed that consists of wide-ranging stratigraphic<br />

intervals (often composed of multiple groups and formations) and<br />

was the basis for an initial assessment of potential reservoirs and<br />

cap rock units that could be regionally mapped using existing data<br />

sources. Maryland and Michigan were later added to the partnership<br />

and the process and list had to be repeated and slightly modified.<br />

Where possible, we adapted previously chosen mapping units to<br />

for use within the new states. However, the addition of the coastal<br />

plain and inclusion of the entire Michigan basin required adding additional<br />

units to the selection list.<br />

After the list of geologic intervals and/or individual units to be<br />

mapped was finalized and a database schema devised, individual<br />

states of the team started collecting the data available to them. This<br />

included, amoung other things, oil-and-gas-well data files (both<br />

electronic and paper), previously completed geologic mapping databases,<br />

published and unpublished studies within individual states,<br />

and miscellaneous data (i.e., core and sample records, geochemical<br />

analyses, miscellaneous geologic data files). As time permitted and<br />

as data sources were discovered, some individual units were added<br />

to the mapping list—an example of this addition is the inclusion of<br />

the Niagaran reefs and Sylvania Sandstone. Table 1 is a final list of<br />

all mapped units in the <strong>MRCSP</strong> project.<br />

Nine potential reservoir horizons and five potential cap-rock intervals<br />

(including organic shales that can also be considered potential<br />

reservoirs) were chosen for regional mapping and further analyses<br />

after our initial screening. Our selection of which reservoir and seal<br />

intervals to map is by no means all-inclusive for the region. On the<br />

contrary, throughout our <strong>Phase</strong> I analysis, several other prospective<br />

reservoirs were noted. Additionally, the selected intervals do not<br />

necessarily represent laterally continuous zones of homogenous reservoirs<br />

or seals. Many assumptions are necessary when mapping at<br />

such a regional scale. Considering the magnitude of this project, the<br />

calculated volumes of potential CO 2 that can sequestered may vary

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