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Nondestructive testing of defects in adhesive joints

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found to be 80.51 and 77.31, respectively. The crystall<strong>in</strong>e material <strong>in</strong> the total cellulose was<br />

expressed by crystall<strong>in</strong>ity <strong>in</strong>dex, which is an empirical measure <strong>of</strong> relative crystall<strong>in</strong>ity.<br />

Crystall<strong>in</strong>ity <strong>in</strong>dex <strong>of</strong> flax was found to be 0.7580 whereas, <strong>in</strong> case <strong>of</strong> flax-g-poly(MA),<br />

crystall<strong>in</strong>ity <strong>in</strong>dex has been found to be 0.7065. The <strong>in</strong>corporation <strong>of</strong> monomer cha<strong>in</strong>s to the<br />

back-bone <strong>of</strong> flax had impaired the crystall<strong>in</strong>ity <strong>of</strong> flax fiber. Therefore, graft<strong>in</strong>g decreased the<br />

crystall<strong>in</strong>ity <strong>of</strong> flax with reduction <strong>in</strong> its stiffness and hardness.<br />

Mechanical properties <strong>of</strong> Orig<strong>in</strong>al flax and Graft Copolymers Re<strong>in</strong>forced Phenol-<br />

Formaldehyde Composites<br />

Wear Test<br />

In case <strong>of</strong> phenol-formaldehyde composites, material loss takes place by the mechanism <strong>of</strong><br />

abrasion and frictional heat generated due to slid<strong>in</strong>g. Moreover, re<strong>in</strong>forcement with graft<br />

copolymer improves the wear resistance as compared to re<strong>in</strong>forcement with orig<strong>in</strong>al flax. Wear<br />

rate with orig<strong>in</strong>al flax re<strong>in</strong>forced composites was much more at all loads. The wear rate was<br />

further enhanced with <strong>in</strong>crease <strong>in</strong> load. In case <strong>of</strong> re<strong>in</strong>forcement <strong>of</strong> the phenol-formaldehyde<br />

matrix with graft copolymer, a reduced wear rate has been obta<strong>in</strong>ed. Maximum weight loss has<br />

been found <strong>in</strong> case <strong>of</strong> phenol-formaldehyde matrix followed by re<strong>in</strong>forcement with orig<strong>in</strong>al flax.<br />

Graft copolymer re<strong>in</strong>forced PF composites showed better wear resistance <strong>in</strong> comparison to<br />

orig<strong>in</strong>al flax re<strong>in</strong>forcement and PF matrix [9-13]. Results have been depicted <strong>in</strong> Table 3.<br />

Tensile Strength<br />

Composites re<strong>in</strong>forced with orig<strong>in</strong>al flax can bear load upto 162 N and showed more extension<br />

(2.37 mm), whereas composites re<strong>in</strong>forced with graft copolymer showed 1.92 mm extension at<br />

load 235 N and PF matrix showed less extension (1.88 mm) and gets failure at load 125 N [9-13]<br />

(Table 3).<br />

Compressive Strength<br />

It is evident from Table 3 that pure phenol-formaldehyde matrix blocks have been observed<br />

with least compressive strength and could not withstand beyond 212 N with compression <strong>of</strong> 1.62<br />

mm. Composites re<strong>in</strong>forced with graft copolymer showed less compression (0.78 mm) and can<br />

bear load upto 814 N, whereas composite re<strong>in</strong>forced with orig<strong>in</strong>al flax showed 1.32 mm<br />

compression and gets failure at 372 N [9-13].<br />

4

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