Homoleptische Methylverbindungen von Elementen der 4. und 5 ...

Praktischer Teil
Tab. 76 Anisotropic displacement parameters (10 -1 pm 2 ) for [Li{O(C H ) } ][Ti (CH ) ]. The anisotro-
2 5 2 3 2 3 9
pic displacement factor exponent takes the form: -2π 2 [ h 2 a 2 U11 + ... + 2 h k a* b* U12 ]
U11 U22 U33 U23 U13 U12
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Ti(1) 35(1) 36(1) 32(1) -8(1) 9(1) -2(1)
Ti(2) 30(1) 43(1) 32(1) 8(1) 9(1) -2(1)
Ti(3) 29(1) 32(1) 31(1) -1(1) 8(1) -1(1)
Ti(4) 33(1) 34(1) 32(1) 4(1) 8(1) -3(1)
C(8) 33(2) 40(2) 37(2) -3(2) 8(2) -1(2)
C(1) 27(2) 36(2) 40(2) 2(2) 5(2) 0(2)
C(2) 37(2) 47(2) 37(2) 4(2) 7(2) 1(2)
C(13) 29(2) 42(2) 41(2) 1(2) 4(2) -1(2)
C(9) 39(2) 55(2) 54(3) 8(2) 1(2) 1(2)
C(12) 44(2) 36(2) 43(2) -4(2) 16(2) 1(2)
C(10) 52(2) 41(2) 63(3) -10(2) 22(2) -11(2)
C(6) 64(3) 38(2) 46(2) -7(2) 19(2) 7(2)
C(3) 45(2) 46(2) 70(3) -1(2) 21(2) -2(2)
C(7) 42(3) 84(3) 71(3) -34(3) 4(2) 2(2)
C(4) 47(2) 53(2) 45(2) -2(2) 13(2) 0(2)
C(5) 48(2) 49(2) 36(2) -12(2) 6(2) 5(2)
C(11) 36(2) 45(2) 43(2) 2(2) 14(2) 1(2)
C(14) 39(2) 46(2) 41(2) -11(2) 11(2) 1(2)
C(15) 48(2) 49(2) 45(2) 14(2) 8(2) -8(2)
C(16) 63(3) 60(3) 56(3) 1(2) 26(2) -21(2)
C(17) 64(3) 72(3) 46(2) 25(2) 6(2) -16(2)
C(18) 51(3) 82(3) 54(3) 32(2) 10(2) -9(2)
O(1) 57(2) 47(2) 34(1) 9(1) 23(1) 11(1)
O(2) 40(1) 48(2) 39(1) -4(1) 15(1) -3(1)
O(3) 36(1) 50(2) 35(1) -2(1) 14(1) 1(1)
O(4) 64(2) 48(2) 38(2) -7(1) 28(1) -1(1)
O(5) 42(1) 35(1) 26(1) -1(1) 3(1) 6(1)
O(6) 39(1) 35(1) 27(1) 2(1) 6(1) -2(1)
C(71) 82(3) 54(3) 55(3) 19(2) 8(2) 9(2)
C(72) 62(3) 42(2) 52(3) 8(2) 21(2) 1(2)
C(73) 215(7) 102(5) 160(6) 63(4) 155(6) 68(5)
C(74) 76(3) 89(4) 56(3) -2(2) 37(3) 12(3)
C(21) 102(4) 95(4) 48(3) 7(3) 32(3) 15(3)
C(22) 72(3) 38(2) 49(3) -3(2) 22(2) 4(2)
C(23) 41(3) 87(3) 84(4) 20(3) 29(2) -8(2)
C(24) 38(2) 56(3) 100(4) -22(3) 10(3) 4(2)
C(31) 51(3) 84(3) 67(3) 8(3) 10(2) 18(2)
C(32) 38(3) 103(4) 66(3) -25(3) 21(2) 1(2)
C(33) 76(3) 36(2) 57(3) 11(2) 28(2) -1(2)
C(34) 77(3) 81(3) 39(2) 5(2) 17(2) 1(3)
C(41) 112(4) 59(3) 56(3) -18(2) 20(3) -8(3)
C(42) 74(3) 41(2) 57(3) -14(2) 27(2) -8(2)
C(43) 320(10) 107(5) 220(8) -73(5) 235(8) -94(6)
C(44) 80(4) 139(5) 43(3) 8(3) 32(3) 0(3)
C(51) 80(3) 44(2) 59(3) 8(2) 4(2) 22(2)
C(52) 54(2) 43(2) 37(2) 6(2) 5(2) 0(2)
C(53) 53(2) 46(2) 33(2) -4(2) 0(2) 13(2)
C(54) 69(3) 51(3) 59(3) -10(2) -9(2) -3(2)
C(61) 64(3) 51(3) 56(3) 7(2) -8(2) 10(2)
C(62) 49(2) 41(2) 30(2) 5(2) 4(2) -6(2)
C(63) 58(2) 41(2) 34(2) -7(2) 7(2) 1(2)
C(64) 79(3) 45(2) 65(3) -7(2) 6(2) -20(2)
Li(2) 41(3) 37(3) 35(3) 2(3) 10(3) -1(3)
Li(1) 46(4) 39(3) 33(3) 3(3) 9(3) 0(3)
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103