Homoleptische Methylverbindungen von Elementen der 4. und 5 ...
Homoleptische Methylverbindungen von Elementen der 4. und 5 ...
Homoleptische Methylverbindungen von Elementen der 4. und 5 ...
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Fortsetzung Tab. 32<br />
B(42) 4125(11) 4772(9) 4952(10) 86(4)<br />
B(43) 4883(13) 5607(9) 5574(10) 97(4)<br />
B(51) 4306(10) 426(8) 4519(8) 79(4)<br />
B(52) 4087(11) -235(9) 5015(10) 89(4)<br />
B(53) 4801(12) -662(9) 5490(9) 92(4)<br />
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Tab. 33 Bond lengths [pm] and angles [°] for [Li(THF) 4 ][Ta(C 6 H 5 ) 6 ]·4 C 6 H 6 .<br />
Ta(1)-C(51) 223.5(10)<br />
Ta(1)-C(41) 223.8(9)<br />
Ta(1)-C(61) 22<strong>4.</strong>0(10)<br />
Ta(1)-C(31) 22<strong>4.</strong>1(10)<br />
Ta(1)-C(21) 225.2(10)<br />
Ta(1)-C(11) 228.6(9)<br />
C(11)-C(16) 135.8(15)<br />
C(11)-C(12) 138.9(14)<br />
C(12)-C(13) 141.8(15)<br />
C(13)-C(14) 133.7(18)<br />
C(14)-C(15) 138.2(19)<br />
C(15)-C(16) 142.4(16)<br />
C(21)-C(22) 138.3(15)<br />
C(21)-C(26) 138.9(14)<br />
C(22)-C(23) 142.7(16)<br />
C(23)-C(24) 132.9(17)<br />
C(24)-C(25) 135.0(18)<br />
C(25)-C(26) 137.9(16)<br />
C(31)-C(32) 138.3(14)<br />
C(31)-C(36) 140.2(14)<br />
C(32)-C(33) 140.0(14)<br />
C(33)-C(34) 13<strong>4.</strong>8(15)<br />
C(34)-C(35) 132.4(16)<br />
C(35)-C(36) 138.7(15)<br />
C(41)-C(46) 132.9(15)<br />
C(41)-C(42) 142.7(14)<br />
C(42)-C(43) 138.3(15)<br />
C(43)-C(44) 13<strong>4.</strong>4(17)<br />
C(44)-C(45) 136.3(17)<br />
C(45)-C(46) 141.0(16)<br />
C(51)-C(52) 137.7(15)<br />
C(51)-C(56) 139.3(14)<br />
C(52)-C(53) 138.7(15)<br />
C(53)-C(54) 13<strong>4.</strong>6(15)<br />
C(54)-C(55) 133.9(17)<br />
C(55)-C(56) 137.3(17)<br />
C(61)-C(62) 138.1(14)<br />
C(61)-C(66) 138.2(14)<br />
C(62)-C(63) 138.1(15)<br />
C(63)-C(64) 136.5(15)<br />
C(64)-C(65) 140.5(15)<br />
C(65)-C(66) 138.1(15)<br />
O(1)-Li 192.4(19)<br />
O(2)-Li 191(3)<br />
O(3)-Li 196(2)<br />
O(4)-Li 185(3)<br />
C(51)-Ta(1)-C(41) 86.5(4)<br />
C(51)-Ta(1)-C(61) 142.7(4)<br />
Praktischer Teil<br />
C(41)-Ta(1)-C(61) 77.4(3)<br />
C(51)-Ta(1)-C(31) 120.3(4)<br />
C(41)-Ta(1)-C(31) 145.6(4)<br />
C(61)-Ta(1)-C(31) 89.6(4)<br />
C(51)-Ta(1)-C(21) 87.2(4)<br />
C(41)-Ta(1)-C(21) 82.7(4)<br />
C(61)-Ta(1)-C(21) 123.0(4)<br />
C(31)-Ta(1)-C(21) 78.0(3)<br />
C(51)-Ta(1)-C(11) 76.5(3)<br />
C(41)-Ta(1)-C(11) 125.3(4)<br />
C(61)-Ta(1)-C(11) 85.7(4)<br />
C(31)-Ta(1)-C(11) 8<strong>4.</strong>5(3)<br />
C(21)-Ta(1)-C(11) 145.7(4)<br />
C(16)-C(11)-C(12) 118.7(9)<br />
C(16)-C(11)-Ta(1) 11<strong>4.</strong>7(8)<br />
C(12)-C(11)-Ta(1) 126.5(7)<br />
C(11)-C(12)-C(13) 119.0(11)<br />
C(14)-C(13)-C(12) 122.3(12)<br />
C(13)-C(14)-C(15) 119.3(11)<br />
C(14)-C(15)-C(16) 119.0(12)<br />
C(11)-C(16)-C(15) 121.6(12)<br />
C(22)-C(21)-C(26) 113.4(10)<br />
C(22)-C(21)-Ta(1) 119.6(8)<br />
C(26)-C(21)-Ta(1) 126.9(8)<br />
C(21)-C(22)-C(23) 123.3(11)<br />
C(24)-C(23)-C(22) 118.8(12)<br />
C(23)-C(24)-C(25) 120.0(11)<br />
C(24)-C(25)-C(26) 120.7(12)<br />
C(25)-C(26)-C(21) 123.1(12)<br />
C(32)-C(31)-C(36) 11<strong>4.</strong>3(9)<br />
C(32)-C(31)-Ta(1) 118.1(7)<br />
C(36)-C(31)-Ta(1) 127.1(8)<br />
C(31)-C(32)-C(33) 12<strong>4.</strong>0(9)<br />
C(34)-C(33)-C(32) 117.6(10)<br />
C(35)-C(34)-C(33) 121.5(10)<br />
C(34)-C(35)-C(36) 121.3(10)<br />
C(35)-C(36)-C(31) 121.2(11)<br />
C(46)-C(41)-C(42) 115.9(10)<br />
C(46)-C(41)-Ta(1) 115.6(8)<br />
C(42)-C(41)-Ta(1) 128.3(8)<br />
C(43)-C(42)-C(41) 120.0(11)<br />
C(44)-C(43)-C(42) 121.5(11)<br />
C(43)-C(44)-C(45) 120.2(11)<br />
C(44)-C(45)-C(46) 117.9(11)<br />
C(41)-C(46)-C(45) 12<strong>4.</strong>3(11)<br />
C(52)-C(51)-C(56) 115.9(9)<br />
C(52)-C(51)-Ta(1) 113.1(7)<br />
C(56)-C(51)-Ta(1) 130.0(8)<br />
C(51)-C(52)-C(53) 123.2(9)<br />
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