03.07.2013 Views

download 21.6mb - Oil-Spill-Info.com

download 21.6mb - Oil-Spill-Info.com

download 21.6mb - Oil-Spill-Info.com

SHOW MORE
SHOW LESS

Create successful ePaper yourself

Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.

CONCLUSIONS<br />

A number of specific conclusions concerning the levels of AMOCO<br />

CADIZ petroleum hydrocarbons in various environmental <strong>com</strong>partments, the<br />

changing chemistry of the hydrocarbon assemblages, and the persistence<br />

of petroleum in these <strong>com</strong>partments are presented here.<br />

1) Upon introduction into the environment, the oil weathered<br />

rapidly with evaporation and biodegradation changing the oil's<br />

chemistry markedly even prior to landfall.<br />

2) <strong>Oil</strong> impacted a variety of intertidal sedimentary types and a<br />

number of secondary impacts were noted at many stations.<br />

3) <strong>Oil</strong> was buried in most sedimentary environments with burial<br />

and/or penetration down to 15 cm in fine-grained sediments and<br />

deeper (^20-30 cm) in sandy sediment.<br />

4) <strong>Oil</strong> remained less biodegraded in sandy beach environments than<br />

in fine-grained sediments in which heavily biodegraded oil was<br />

characteristic.<br />

5) The presence of UCM material, pentacyclic triterpanes, and<br />

alkylated phenanthrene and dibenzothiophene <strong>com</strong>pounds remain<br />

as characteristic chemical features of AMOCO CADIZ oil in<br />

sediments.<br />

6) Less weathered oil appeared to be buried (10-20 cm) in finegrained<br />

sediments as evidenced in samples taken one year after<br />

the spill.<br />

7) Offshore sediments were impacted after the shoreline impact,<br />

probably through processes involving beaching, sorption on<br />

intertidal sediments, and offshore transport of these sediments.<br />

Samples taken after the spill in April 1978 do not<br />

reveal AMOCO CADIZ oil, thus indicating a lag (weeks to<br />

months) in offshore deposition.<br />

8) Surface intertidal sediments taken in June 1981 show that<br />

"normal" background inputs, both of biogenic and chronic<br />

pollutant origins, have replaced AMOCO CADIZ oil as major<br />

<strong>com</strong>ponents of the hydrocarbon geochemistry. Only at the most<br />

impacted stations at lie Grande marsh and within the sandy<br />

beach sediment at AMC-4 (Portsall) do identifiable AMOCO<br />

residues persist. At lie Grande the aromatic marker <strong>com</strong>pounds<br />

are absent, but hopanoid <strong>com</strong>pounds (triterpanes) and a large<br />

UCM persist.<br />

97

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!