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The degradations observed in these sediments results in :<br />

- the progressive disappearance of saturated hydrocarbons, principally<br />

the normal paraffins ;<br />

- the disappearance of the light aromatic hydrocarbons ;<br />

- the oxidation of the polar <strong>com</strong>pounds (esters, acids, etc...).<br />

The <strong>com</strong>pounds which persist are :<br />

- the saturated polycyclic hydrocarbons and the heavy aromatics ;<br />

- sulfurous aromatic hydrocarbons of the thiophenic type ;<br />

- resins and asphaltenes, resulting in stable metal (nickel and vana-<br />

dium) and sulfur contents.<br />

In the sediments samples in the area of the Aber, terrigenic de-<br />

posits are superposed on the Amoco Cadiz crude, resulting in :<br />

- an increase in polar <strong>com</strong>pounds — resins and asphaltenes. The increase<br />

in asphaltene contents is due to the presence of pigment<br />

(green) of chlorophyllaceous origin ;<br />

- the appearance of n-alkanes of odd carbon numbers (n-C25 through<br />

n-C33) .<br />

The most striking evolution in the "chocolate mousse" samples is<br />

the loss of light hydrocarbons due to evaporation and dissolution.<br />

Volatile <strong>com</strong>pounds under C14 were not considered in this report.<br />

The samples of polluted sand taken from the beaches a year after<br />

the accident show a degradation phenomenon principally affecting the<br />

saturated hydrocarbons, and among these, principally the n-paraffins.<br />

There is an increase in the contents of polar <strong>com</strong>pounds. But our information<br />

is not adequate to state at what point in the history of<br />

these samples, the degradation was most intense.<br />

141

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