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tesi R. Miscioscia.pdf - EleA@UniSA

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24 Working Principles<br />

In the [x0,L] region, the density of free charge is very low if compared<br />

with the channel ([0,x0]), then we can approximate the character of IDS<br />

as shown in (eq. 26):<br />

eq. 26<br />

E<br />

x<br />

( x)<br />

>> E ( x ) ≈E<br />

( 0)<br />

⇒ I<br />

⇒ I<br />

DS<br />

DS<br />

∝<br />

x<br />

0<br />

W<br />

≈ ε chμn<br />

t<br />

L − x<br />

( ( ) )<br />

( ) 3<br />

VDS<br />

−V<br />

x0<br />

L − x<br />

0<br />

x<br />

0<br />

ch<br />

2<br />

∀x<br />

> x ⇒<br />

2 ( E ( L)<br />

) W ⎛V<br />

( L)<br />

−V<br />

( x )<br />

x<br />

This explains the power-law behavior shown in figure 3 for high D to<br />

S fields.<br />

1.4 Thermally activated conduction and<br />

compensation rules.<br />

The dependence of charge mobility in organic semiconductor<br />

channels from temperature and gate fields for OTFT devices is one of<br />

the subjects which have attracted the attention of the recent literature<br />

studies [4][5][6][7] in the last years but still today, the charge<br />

transport in such materials is still not fully understood.<br />

In organic semiconductors, such dependence has been described in<br />

terms of multiple charge trapping [14]), hopping [7], charge diffusion<br />

processes [4] etc. by starting from common evidence which is the<br />

starting point for all these models developments: the dependence of<br />

the thermal activation energy Ea for the mobility from the gate<br />

voltage. In particular, we are referring to a phenomenon which for the<br />

matter of simplicity we will call X (i.e. conductivity activation in the<br />

active region of the OTFT) and evidencing a thermally-activated<br />

behavior and following an exponential Arrhenius-like law versus the<br />

temperature (see eq. 27).<br />

eq. 27 <br />

<br />

2<br />

0<br />

≈ ε chμn<br />

t<br />

L − x<br />

0<br />

ch<br />

⎜<br />

⎝<br />

L − x<br />

0<br />

0<br />

⎞<br />

⎟<br />

⎠<br />

2<br />

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