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tesi R. Miscioscia.pdf - EleA@UniSA

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Chapter 2 59<br />

figure 28: Pentacene based OTFT transcharacteristics changing the titanium oxide nanoparticles in<br />

the dielectric polymeric matrix [29].<br />

2.6.2 Self-assembled dielectrics<br />

Self-assembled (SA) films can be used to realize an extremely<br />

thin (2 to 6nm) and virtually free of defects gate insulator obtaining, at<br />

the same time, dielectric strength of the order of tens of MV/cm as<br />

shown in the table of figure 29.<br />

figure 29: evolution in the state of the art for the self assembled dielectrics [30].<br />

Among the characteristics of the SA dielectrics, there is of<br />

course the possibility to obtain high gate capacitance, but also the<br />

advantage of being able to be realized by means of solution process,<br />

therefore with low complexity and cost (dipping, spin coating, IJP,<br />

etc.). For these and other reasons, they have attracted, over the years,<br />

great interest in the scientific community reaching quite encouraging<br />

results. For example, in the case of pentacene transistors, at this point

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