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Sampling Guide for Air Contaminants in the Workplace - Irsst

Sampling Guide for Air Contaminants in the Workplace - Irsst

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ROHS Substances table<br />

95<br />

ROHS Name<br />

CAS<br />

TWAEV<br />

STEV<br />

Ceil<strong>in</strong>g<br />

(mg/m³)<br />

Notes<br />

<strong>Sampl<strong>in</strong>g</strong><br />

Device<br />

Flow<br />

L/m<strong>in</strong><br />

Volume<br />

TWAEV<br />

STEV<br />

(L)<br />

Pr<strong>in</strong>ciple<br />

MRV<br />

µg<br />

CVa<br />

(%)<br />

#<br />

meth.<br />

Remarks<br />

2-Methoxyethanol<br />

(EGME)<br />

109-86-4<br />

16 Pc SKC 226-01 activated charcoal tube<br />

Max: 10 GC-FID 9,6 5,1 IRSST<br />

138-3<br />

2120 Activated charcoal 100/50 mg<br />

0,2<br />

The analysis of 2-Methoxyethanol must be specifically sampled due to a specific<br />

desorption solvent.<br />

However, simultaneous sampl<strong>in</strong>g and analysis of <strong>the</strong> 2-Ethoxyethanol is possible.<br />

2-Methoxyethyl acetate<br />

(EGMEA)<br />

110-49-6<br />

24 Pc SKC 226-01 activated charcoal tube<br />

Max: 10 GC-FID 15 1,0 IRSST<br />

139-2<br />

2120 Activated charcoal 100/50 mg<br />

0,2<br />

4-Methoxyphenol<br />

150-76-5<br />

5 XAD-7 tube 100/50 mg<br />

0,2 20 GC-FID<br />

OSHA<br />

IMISM329<br />

Contact <strong>the</strong> IRSST be<strong>for</strong>e sampl<strong>in</strong>g.<br />

Methyl acetate<br />

79-20-9<br />

606<br />

757<br />

3M 3500 organic vapour monitor<br />

2695 Passive dosimeter<br />

0,037 GC-FID 215<br />

IRSST<br />

136-1<br />

For <strong>the</strong> monitors, <strong>the</strong> flow must be considered as be<strong>in</strong>g a sampl<strong>in</strong>g rate.<br />

Accord<strong>in</strong>g to <strong>the</strong> data from 3M, <strong>the</strong> precision (CVsampl<strong>in</strong>g) of <strong>the</strong> sampl<strong>in</strong>g rate is<br />

1.6%. Refer to <strong>the</strong> 3M passive monitor guide on <strong>the</strong> IRSST's Web site.<br />

Methyl acetate<br />

79-20-9<br />

606<br />

757<br />

SKC 226-01 activated charcoal tube<br />

2120 Activated charcoal 100/50 mg<br />

Max:<br />

0,2<br />

7<br />

3<br />

GC-FID<br />

215<br />

IRSST<br />

136-1<br />

The analysis can be done by gas chromatography coupled with mass<br />

spectrometry (GC-MS, IRSST method# 369); <strong>in</strong> this case <strong>the</strong> analytical<br />

uncerta<strong>in</strong>ty (Cva) is 0.55%.<br />

Methyl acetylene<br />

74-99-7<br />

1640 Alum<strong>in</strong>ized sampl<strong>in</strong>g bag<br />

0,01- 3 GC-FID<br />

NIOSH<br />

S84<br />

0,05<br />

Contact <strong>the</strong> IRSST be<strong>for</strong>e sampl<strong>in</strong>g.<br />

Methyl acetylenepropadiene<br />

mixture<br />

(MAPP)<br />

1640<br />

2050<br />

Alum<strong>in</strong>ized sampl<strong>in</strong>g bag<br />

0,01-<br />

0,05<br />

3 GC-FID<br />

NIOSH<br />

S85<br />

Contact <strong>the</strong> IRSST be<strong>for</strong>e sampl<strong>in</strong>g.<br />

59355-75-8<br />

Methyl acrylate<br />

96-33-3<br />

7 Pc<br />

S<br />

Activated charcoal tube impregnated with<br />

4-tert-butylcatechol (TBC)<br />

2189 Activated charcoal with TBC<br />

0,05 GC-FID 3 2,1<br />

12 IRSST<br />

146-2<br />

Methyl acrylate must be sampled specifically due to <strong>the</strong> sampl<strong>in</strong>g device used.<br />

However, simultaneous sampl<strong>in</strong>g and analysis of ethyl acrylate est possible.<br />

Methyl alcohol<br />

67-56-1<br />

262<br />

328<br />

Pc Silica gel tube #SKC 226-10<br />

0,1 3 GC-FID 60 6,7<br />

2140 Silica gel 150/75 mg<br />

1,5<br />

IRSST<br />

92<br />

Methanol must be sampled specifically due to <strong>the</strong> sampl<strong>in</strong>g device used and a<br />

specific desorption solvent.

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