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Sampling Guide for Air Contaminants in the Workplace - Irsst

Sampling Guide for Air Contaminants in the Workplace - Irsst

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ROHS Substances table<br />

102<br />

ROHS Name<br />

CAS<br />

TWAEV<br />

STEV<br />

Ceil<strong>in</strong>g<br />

(mg/m³)<br />

Notes<br />

<strong>Sampl<strong>in</strong>g</strong><br />

Device<br />

Flow<br />

L/m<strong>in</strong><br />

Volume<br />

TWAEV<br />

STEV<br />

(L)<br />

Pr<strong>in</strong>ciple<br />

MRV<br />

µg<br />

CVa<br />

(%)<br />

#<br />

meth.<br />

Remarks<br />

Nickel, Metal<br />

7440-02-0<br />

1 Mixed cellulose ester filter, 0.8µm, 25 and 1,5 180 ICP-MS 2 3,89 IRSST<br />

362<br />

37 mm.<br />

905 MCE filter-37<br />

915 MCE filter-25<br />

Cassettes 913 or 916, whose filters are preweighed, can also be used. For<br />

surface wipe sampl<strong>in</strong>g, contact Laboratory Customer Service.<br />

The analytical results are expressed as total nickel.<br />

Nickel [7440-02-0],<br />

Insoluble compounds<br />

(as Ni)<br />

1 Mixed cellulose ester filter, 0.8µm, 25 and 1,5 180 ICP-MS 2 3,89 IRSST<br />

362<br />

37 mm.<br />

905 MCE filter-37<br />

915 MCE filter-25<br />

Cassettes 913 or 916, whose filters are preweighed, can also be used. For<br />

surface wipe sampl<strong>in</strong>g, contact Laboratory Customer Service.<br />

The analytical results are expressed as total nickel.<br />

Nickel [7440-02-0],<br />

Soluble compounds (as<br />

Ni)<br />

0,1 Gelman 60714 polyv<strong>in</strong>yl chloride filter 1,5 180 FAAS 2 4,3 IRSST<br />

214-2<br />

903 PVC filter-37<br />

Specific sampl<strong>in</strong>g must be carried out <strong>for</strong> this substance.<br />

The analytical results are expressed as total soluble nickel.<br />

Nickel carbonyl (as Ni)<br />

13463-39-3<br />

0,007 Mixed cellulose ester filter <strong>in</strong> series with a 0,05- 80 ET-AAS<br />

NIOSH<br />

6007<br />

charcoal tube with low nickel content<br />

0,2<br />

Contact <strong>the</strong> IRSST be<strong>for</strong>e sampl<strong>in</strong>g.<br />

Nickel sulfide roast<strong>in</strong>g,<br />

fume and dust (as Ni)<br />

1 C1<br />

RP<br />

EM<br />

Contact <strong>the</strong> IRSST be<strong>for</strong>e sampl<strong>in</strong>g.<br />

IRSST method 362 is <strong>for</strong> certa<strong>in</strong> metals by ICP-MS and can be adapted to nickel<br />

sulfide.<br />

Nicot<strong>in</strong>e<br />

54-11-5<br />

0,5 Pc SKC 226-30-04 XAD-2 tube<br />

1,0 100 GC-NPD 0,5 4,0 IRSST<br />

233-1<br />

2152 XAD-2 100/50 mg<br />

Nicot<strong>in</strong>e must be sampled specifically due to <strong>the</strong> sampl<strong>in</strong>g device used and <strong>the</strong><br />

specific desorption solvent.<br />

Nitrapyr<strong>in</strong><br />

1929-82-4<br />

10<br />

20<br />

OVS-2 tube with XAD-2 and glass fiber<br />

filter<br />

1 480 HPLC-UV<br />

15<br />

OSHA<br />

IMIS0684<br />

Contact <strong>the</strong> IRSST be<strong>for</strong>e sampl<strong>in</strong>g.<br />

Nitric acid<br />

7697-37-2<br />

5,2<br />

10<br />

Treated silica gel tube SKC 226-10-03<br />

2147 Silica gel 400/200 mg<br />

0,2 48 IC-CD 5,1 3,55<br />

3<br />

IRSST<br />

211-1<br />

Five ions can be determ<strong>in</strong>ed simultaneously, namely bromide, chloride, nitrate,<br />

phosphate and sulfate.<br />

Analytical results are expressed as hydrobromic, hydrochloric, nitric, phosphoric<br />

and sulfuric acid.<br />

Samples are stable <strong>for</strong> 21 days at 25°C.<br />

All <strong>the</strong> nitrate ions not orig<strong>in</strong>at<strong>in</strong>g from <strong>the</strong> acid can cause positive <strong>in</strong>terference.

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