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Sampling Guide for Air Contaminants in the Workplace - Irsst

Sampling Guide for Air Contaminants in the Workplace - Irsst

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ROHS Substances table<br />

41<br />

ROHS Name<br />

CAS<br />

TWAEV<br />

STEV<br />

Ceil<strong>in</strong>g<br />

(mg/m³)<br />

Notes<br />

<strong>Sampl<strong>in</strong>g</strong><br />

Device<br />

Flow<br />

L/m<strong>in</strong><br />

Volume<br />

TWAEV<br />

STEV<br />

(L)<br />

Pr<strong>in</strong>ciple<br />

MRV<br />

µg<br />

CVa<br />

(%)<br />

#<br />

meth.<br />

Remarks<br />

Acetaldehyde<br />

75-07-0<br />

--<br />

--<br />

45<br />

C3<br />

RP<br />

Supelco 2-0257 Orbo 23 tube<br />

2186 Orbo 23 120/60 mg<br />

0,1 GC-MS 0,09<br />

10 IRSST<br />

322-1<br />

Be<strong>for</strong>e and after sampl<strong>in</strong>g, tubes must be stored <strong>in</strong> a freezer.<br />

Eleven aldehydes are determ<strong>in</strong>ed simultaneously: acetaldehyde,<br />

isobutyraldehyde, isovaleraldehyde, propionaldehyde, butyraldehyde, furfural,<br />

heptanal, hexanal, valeraldehyde, acrole<strong>in</strong> and <strong>for</strong>maldehyde. This method must<br />

not be used <strong>for</strong> <strong>the</strong> specific evaluation of <strong>for</strong>maldehyde; <strong>the</strong> methods to be used<br />

<strong>in</strong> this case are 295-1 and 357-1.<br />

Acetic acid<br />

64-19-7<br />

25<br />

37<br />

SKC 226-01 activated charcoal tube<br />

2120 Activated charcoal 100/50 mg<br />

1 HPLC-UV 40<br />

50 IRSST<br />

195-2<br />

Acetic acid must be sampled specifically.<br />

Acetic anhydride<br />

108-24-7<br />

21 Glass fiber filter impregnated with 1-(2- 0,05 0,75 GC-NPD<br />

OSHA<br />

82<br />

pyridyl) piperaz<strong>in</strong>e<br />

Any compound that reacts with 1-(2-pyridyl) piperaz<strong>in</strong>e can cause <strong>in</strong>terference.<br />

Contact <strong>the</strong> IRSST be<strong>for</strong>e sampl<strong>in</strong>g.<br />

Acetone<br />

67-64-1<br />

1190<br />

2380<br />

SKC 226-01 activated charcoal tube<br />

2120 Activated charcoal 100/50 mg<br />

Max:<br />

0,2<br />

2<br />

1,5<br />

GC-FID<br />

180 1,2<br />

IRSST<br />

22-2<br />

The analysis can be done by gas chromatography coupled with mass<br />

spectrometry (GC-MS, IRSST method #369); <strong>in</strong> this case <strong>the</strong> analytical<br />

uncerta<strong>in</strong>ty (CVa) is 1.3%.<br />

Acetone<br />

67-64-1<br />

1190<br />

2380<br />

3M Organic Vapor Monitor #3500<br />

2695 Passive dosimeter<br />

0,0401 GC-FID 180 1,2<br />

IRSST<br />

22-2<br />

For <strong>the</strong> monitors, <strong>the</strong> flow must be considered as be<strong>in</strong>g a sampl<strong>in</strong>g rate.<br />

Accord<strong>in</strong>g to <strong>the</strong> data from 3M, <strong>the</strong> precision (CVsampl<strong>in</strong>g) of <strong>the</strong> sampl<strong>in</strong>g rate is<br />

2.2%. Refer to <strong>the</strong> 3M passive monitor guide on <strong>the</strong> IRSST's Web site.<br />

Acetone<br />

67-64-1<br />

1190<br />

2380<br />

DRI-PAD<br />

IRSST<br />

39-A<br />

Refer to <strong>the</strong> user's guide accompany<strong>in</strong>g <strong>the</strong> <strong>in</strong>strument.<br />

Acetone quantification <strong>in</strong> <strong>the</strong> field is done with a direct-read<strong>in</strong>g <strong>in</strong>strument (DRI).<br />

The m<strong>in</strong>imum reported value is 1mg/m³ (0.4 ppm). The method <strong>in</strong> <strong>the</strong> reference<br />

corresponds to DRI calibration.<br />

Acetone cyanohydr<strong>in</strong><br />

75-86-5<br />

--<br />

--<br />

5<br />

Pc<br />

RP<br />

Porapak QS solid adsorbent tube 100/350<br />

mg<br />

0,2 12 GC-NPD<br />

NIOSH<br />

2506<br />

Contact <strong>the</strong> IRSST be<strong>for</strong>e sampl<strong>in</strong>g.<br />

Acetonitrile<br />

75-05-8<br />

67<br />

101<br />

Activated charcoal tube 400/200 mg<br />

0,01-<br />

0,2<br />

25<br />

3<br />

GC-FID<br />

NIOSH<br />

1606<br />

Contact <strong>the</strong> IRSST be<strong>for</strong>e sampl<strong>in</strong>g.<br />

Acetophenone<br />

98-86-2<br />

49 Tenax tube 30/15 mg<br />

0,2 12 GC-FID<br />

OSHA<br />

PV2003<br />

Contact <strong>the</strong> IRSST be<strong>for</strong>e sampl<strong>in</strong>g.

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