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Sampling Guide for Air Contaminants in the Workplace - Irsst

Sampling Guide for Air Contaminants in the Workplace - Irsst

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ROHS Substances table<br />

62<br />

ROHS Name<br />

CAS<br />

TWAEV<br />

STEV<br />

Ceil<strong>in</strong>g<br />

(mg/m³)<br />

Notes<br />

<strong>Sampl<strong>in</strong>g</strong><br />

Device<br />

Flow<br />

L/m<strong>in</strong><br />

Volume<br />

TWAEV<br />

STEV<br />

(L)<br />

Pr<strong>in</strong>ciple<br />

MRV<br />

µg<br />

CVa<br />

(%)<br />

#<br />

meth.<br />

Remarks<br />

Chrysene<br />

218-01-9<br />

C2<br />

RP<br />

EM<br />

Millipore AP4003705 glass fiber filter<br />

pretreated <strong>in</strong> <strong>the</strong> laboratory, <strong>in</strong> series with<br />

a Supelco 2-0264 Orbo-42 tube<br />

2187 Orbo 42 100/50 mg<br />

911 GF filter-37<br />

2 GC-MS 0,1<br />

960 IRSST<br />

225-2<br />

The sampl<strong>in</strong>g tra<strong>in</strong> consists of a cassette that will collect <strong>the</strong> PAHs <strong>in</strong> particulate<br />

<strong>for</strong>m, followed by a tube that will adsorb <strong>the</strong> PAHs <strong>in</strong> vapour <strong>for</strong>m. This tube is<br />

connected directly to <strong>the</strong> pump by Tygon tub<strong>in</strong>g. After sampl<strong>in</strong>g, <strong>the</strong> samples<br />

must be stored <strong>in</strong> <strong>the</strong> freezer protected from light. The tubes and filters must be<br />

shipped toge<strong>the</strong>r. Ten hydrocarbons are determ<strong>in</strong>ed simultaneously:<br />

acenaph<strong>the</strong>ne, fluorene, phenanthrene, anthracene, fluoran<strong>the</strong>ne, pyrene,<br />

chrysene, benz(a)anthracene, benzo(e)pyrene et le benzo(a)pyrene.<br />

Clopidol<br />

2971-90-6<br />

10 SKC 225-8-01-1 or 225-8-04 polyv<strong>in</strong>yl 1,5 180 Grav 25 4,9 IRSST<br />

48-1<br />

chloride filter<br />

902 PVC filter-37<br />

914 PVC filter-25<br />

Additional <strong>in</strong><strong>for</strong>mation is available <strong>in</strong> Info-Labo 91-03. The weight measurement<br />

method <strong>for</strong> dusts is by def<strong>in</strong>ition non-specific.<br />

Coal dust (less than 5%<br />

crystall<strong>in</strong>e silica)<br />

Coal dust (more than<br />

5% crystall<strong>in</strong>e silica)<br />

53570-85-7<br />

2 Pr SKC 225-8-01-1 or 225-8-04 polyv<strong>in</strong>yl 1,7 180 Grav 25 4,9 IRSST<br />

48-1<br />

chloride filter<br />

(nylon)<br />

902<br />

914<br />

PVC filter-37<br />

PVC filter-25<br />

2,75<br />

(GS3)<br />

997 PVC filter-37, 3 parts<br />

0,1 Pr Cyclone <strong>in</strong> series with an Omega P-<br />

1,7 800 XRD 6 5<br />

IRSST<br />

206-2<br />

08370K polyv<strong>in</strong>yl chloride filter<br />

(nylon)<br />

902<br />

997<br />

PVC filter-37<br />

PVC filter-37, 3 parts<br />

2,75<br />

(GS3)<br />

Additional <strong>in</strong><strong>for</strong>mation is available <strong>in</strong> Info-Labo 91-03. The weight measurement<br />

method <strong>for</strong> dusts is by def<strong>in</strong>ition non-specific.<br />

The analytical results are expressed as quartz.<br />

Coal dust (more than<br />

5% crystall<strong>in</strong>e silica)<br />

0,1 Pr Cyclone <strong>in</strong> series with an Omega P-<br />

1,7 800 FTIR 6 5<br />

IRSST<br />

78<br />

08370K polyv<strong>in</strong>yl chloride filter<br />

(nylon)<br />

902<br />

997<br />

PVC filter-37<br />

PVC filter-37, 3 parts<br />

2,75<br />

(GS3)<br />

Coal tar pitch volatiles,<br />

as benzene solubles<br />

65996-93-2<br />

0,2 C1<br />

RP<br />

EM<br />

Millipore AP4003705 glass fiber filter<br />

pretreated <strong>in</strong> <strong>the</strong> laboratory <strong>in</strong> series with<br />

a Supelco 2-0264 Orbo-42 tube<br />

911 GF filter-37<br />

2 960 Grav 50<br />

IRSST<br />

201-1<br />

After sampl<strong>in</strong>g, <strong>the</strong> samples must be stored <strong>in</strong> <strong>the</strong> freezer protected from light.<br />

The gravimetric result is used to establish <strong>the</strong> compliance with <strong>the</strong> standard.<br />

Simultaneous sampl<strong>in</strong>g and analysis of PAHs are possible if <strong>the</strong> complete<br />

sampl<strong>in</strong>g tra<strong>in</strong> is used (see <strong>the</strong> example of benzo(a)pyrene).<br />

Cobalt, elemental and<br />

<strong>in</strong>organic compounds<br />

(as Co)<br />

7440-48-4<br />

0,02 C3 Mixed cellulose ester filter, 0.8µm, 25 and 1,5 180 ICP-MS 0,04 3,15 IRSST<br />

362<br />

37 mm.<br />

905 MCE filter-37<br />

915 MCE filter-25<br />

Cassettes 913 or 916, whose filters are preweighed, can also be used. For<br />

surface wipe sampl<strong>in</strong>g, contact Laboratory Customer Service.<br />

The analytical results are expressed as total cobalt.

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