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Sampling Guide for Air Contaminants in the Workplace - Irsst

Sampling Guide for Air Contaminants in the Workplace - Irsst

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ROHS Substances table<br />

82<br />

ROHS Name<br />

CAS<br />

TWAEV<br />

STEV<br />

Ceil<strong>in</strong>g<br />

(mg/m³)<br />

Notes<br />

<strong>Sampl<strong>in</strong>g</strong><br />

Device<br />

Flow<br />

L/m<strong>in</strong><br />

Volume<br />

TWAEV<br />

STEV<br />

(L)<br />

Pr<strong>in</strong>ciple<br />

MRV<br />

µg<br />

CVa<br />

(%)<br />

#<br />

meth.<br />

Remarks<br />

Formaldehyde<br />

50-00-0<br />

--<br />

--<br />

3<br />

C2<br />

RP<br />

EM<br />

Supelco 2-0257 Orbo 23 tube<br />

2186 Orbo 23 120/60 mg<br />

0,1 GC-MS 3<br />

10 IRSST<br />

329-1<br />

Be<strong>for</strong>e and after sampl<strong>in</strong>g, tubes must be stored <strong>in</strong> a freezer. Additional<br />

<strong>in</strong><strong>for</strong>mation is also available <strong>in</strong> laboratory customer service communiqué SAC-<br />

Labo 2006-08.<br />

Eleven aldehydes are determ<strong>in</strong>ed simultaneously: acetaldehyde,<br />

isobutyraldehyde, isovaleraldehyde, propionaldehyde, butyraldehyde, furfural,<br />

heptanal, hexanal, valeraldehyde, acrole<strong>in</strong>e and <strong>for</strong>maldehyde. This method must<br />

not be used <strong>for</strong> <strong>the</strong> specific evaluation of <strong>for</strong>maldehyde; <strong>the</strong> methods to be used<br />

<strong>in</strong> this case are 295-1 and 357-1.<br />

Formaldehyde<br />

50-00-0<br />

--<br />

--<br />

3<br />

C2<br />

RP<br />

EM<br />

XAD-2 tube impregnated with HMP<br />

2188 XAD-2 120/60 mg impregnated with HMP<br />

Max:<br />

0,1<br />

25 GC-NPD 2 4,5 IRSST<br />

295-1<br />

Formaldehyde must be specifically sampled due to <strong>the</strong> sampl<strong>in</strong>g device used and<br />

a specific desorption solvent. The tubes must be stored <strong>in</strong> <strong>the</strong> freezer be<strong>for</strong>e and<br />

after sampl<strong>in</strong>g. Additional <strong>in</strong><strong>for</strong>mation is also available <strong>in</strong> laboratory customer<br />

service communiqué SAC-Labo 2006-08.<br />

Formaldehyde<br />

50-00-0<br />

--<br />

--<br />

3<br />

C2<br />

RP<br />

EM<br />

DRI-PAD<br />

IRSST<br />

39-A<br />

Refer to <strong>the</strong> user's guide accompany<strong>in</strong>g <strong>the</strong> <strong>in</strong>strument. Additional <strong>in</strong><strong>for</strong>mation is<br />

also available <strong>in</strong> laboratory customer service communiqué SAC-Labo 2006-08.<br />

The m<strong>in</strong>imum reported value is 0.15 mg/m³ (0.12 ppm). The reference method<br />

corresponds to calibration of <strong>the</strong> direct-read<strong>in</strong>g <strong>in</strong>strument (DRI). Formaldehyde<br />

quantified <strong>in</strong> <strong>the</strong> field with a DRI.<br />

Formaldehyde<br />

50-00-0<br />

--<br />

--<br />

3<br />

C2<br />

RP<br />

EM<br />

SKC #500-100 UMEX-100 passive<br />

sampler<br />

6100 Passive sampler<br />

0,0286 HPLC-UV 0,21<br />

IRSST<br />

357-1<br />

Keep <strong>in</strong> freezer be<strong>for</strong>e and after sampl<strong>in</strong>g. For monitors, flow must be<br />

considered as be<strong>in</strong>g a sampl<strong>in</strong>g rate. Additional <strong>in</strong><strong>for</strong>mation is also available <strong>in</strong><br />

<strong>the</strong> laboratory services communiqué SAC-Labo 2006-08.<br />

Stable <strong>for</strong> 3 weeks after sampl<strong>in</strong>g.<br />

Formamide<br />

75-12-7<br />

18 Pc Silica gel tube 150/75 mg<br />

0,1 10 GC-FID<br />

OSHA<br />

IMIS1292<br />

Contact <strong>the</strong> IRSST be<strong>for</strong>e sampl<strong>in</strong>g.<br />

Formic acid<br />

64-18-6<br />

9,4<br />

19<br />

PTFE filter with treated silica gel tube<br />

400/200 mg<br />

0,05-<br />

0,2<br />

24<br />

3<br />

IC-CD<br />

NIOSH<br />

2011<br />

Contact <strong>the</strong> IRSST be<strong>for</strong>e sampl<strong>in</strong>g. The sample is stable <strong>for</strong> 1 week at 25°C.<br />

Furfural<br />

98-01-1<br />

7,9 Pc Supelco 2-0257 Orbo 23 tube<br />

0,1 10 GC-MS 0,11<br />

IRSST<br />

328-1<br />

2186 Orbo 23 120/60 mg<br />

Be<strong>for</strong>e and after sampl<strong>in</strong>g, tubes must be stored <strong>in</strong> a freezer.<br />

Eleven aldehydes are determ<strong>in</strong>ed simultaneously: acetaldehyde,<br />

isobutyraldehyde, isovaleraldehyde, propionaldehyde, butyraldehyde, furfural,<br />

heptanal, hexanal, valeraldehyde, acrole<strong>in</strong> and <strong>for</strong>maldehyde. This method must<br />

not be used <strong>for</strong> <strong>the</strong> specific evaluation of <strong>for</strong>maldehyde; <strong>the</strong> methods to be used<br />

<strong>in</strong> this case are 295-1 and 357-1.<br />

Furfuryl alcohol<br />

98-00-0<br />

40<br />

60<br />

Pc Porapak Q tube #SKC 226-115<br />

Max: 6<br />

2162 Porapak Q 150/75 mg<br />

0,05 0,75<br />

GC-FID<br />

4,7 4,0<br />

IRSST<br />

87-2<br />

Furfuryl alcohol must be sampled specifically due to <strong>the</strong> sampl<strong>in</strong>g device used<br />

and a specific desorption solvent.

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