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Sampling Guide for Air Contaminants in the Workplace - Irsst

Sampling Guide for Air Contaminants in the Workplace - Irsst

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ROHS Substances table<br />

110<br />

ROHS Name<br />

CAS<br />

TWAEV<br />

STEV<br />

Ceil<strong>in</strong>g<br />

(mg/m³)<br />

Notes<br />

<strong>Sampl<strong>in</strong>g</strong><br />

Device<br />

Flow<br />

L/m<strong>in</strong><br />

Volume<br />

TWAEV<br />

STEV<br />

(L)<br />

Pr<strong>in</strong>ciple<br />

MRV<br />

µg<br />

CVa<br />

(%)<br />

#<br />

meth.<br />

Remarks<br />

Phosphoric acid<br />

7664-38-2<br />

1<br />

3<br />

Treated silica gel tube SKC 226-10-03<br />

2147 Silica gel 400/200 mg<br />

0,2 48 IC-CD 5,2 4,68<br />

3<br />

IRSST<br />

211-1<br />

Five ions can be determ<strong>in</strong>ed simultaneously, namely bromide, chloride, nitrate,<br />

phosphate and sulfate.<br />

Analytical results are expressed as hydrobromic, hydrochloric, nitric, phosphoric<br />

and sulfuric acid.<br />

Samples are stable <strong>for</strong> 21 days at 25°C.<br />

All phosphate ions not orig<strong>in</strong>at<strong>in</strong>g from <strong>the</strong> acid can cause positive <strong>in</strong>terference.<br />

Phosphorus (yellow)<br />

7723-14-0<br />

0,1 Tenax-GC tube<br />

0,01- 100 GC-FPD<br />

NIOSH<br />

7905<br />

0,2<br />

A filter can be used if <strong>the</strong> phosphorus is present <strong>in</strong> particulate <strong>for</strong>m. Contact <strong>the</strong><br />

IRSST be<strong>for</strong>e sampl<strong>in</strong>g.<br />

Phosphorus oxychloride<br />

10025-87-3<br />

0,63 Glass fritted tip imp<strong>in</strong>ger conta<strong>in</strong><strong>in</strong>g 10 mL 1 240 IC-CD<br />

OSHA<br />

IMIS2094<br />

of a solution of sodium carbonate and<br />

sodium bicarbonate<br />

Contact <strong>the</strong> IRSST be<strong>for</strong>e sampl<strong>in</strong>g.<br />

Phosphorus<br />

pentachloride<br />

10026-13-8<br />

0,85 Polyv<strong>in</strong>yl chloride filter <strong>in</strong> series with a 0,2 48 Colo<br />

OSHA<br />

IMIS2091<br />

glass fritted tip imp<strong>in</strong>ger conta<strong>in</strong><strong>in</strong>g 15 mL<br />

of deionized water<br />

The use of a sta<strong>in</strong>less steel filter support (#SKC SCN225-26) is suggested. The<br />

filter is thrown away after sampl<strong>in</strong>g. Contact <strong>the</strong> IRSST be<strong>for</strong>e sampl<strong>in</strong>g.<br />

Phosphorus<br />

pentasulfide<br />

1<br />

3<br />

Polyv<strong>in</strong>yl chloride filter<br />

1-2 120 IC-CD<br />

30<br />

OSHA<br />

ID128SG<br />

Contact <strong>the</strong> IRSST be<strong>for</strong>e sampl<strong>in</strong>g.<br />

1314-80-3<br />

Phosphorus trichloride<br />

7719-12-2<br />

1,1<br />

2,8<br />

Glass fritted tip imp<strong>in</strong>ger conta<strong>in</strong><strong>in</strong>g<br />

deionized water<br />

0,05-<br />

0,2<br />

100<br />

3<br />

Colo<br />

NIOSH<br />

6402<br />

Contact <strong>the</strong> IRSST be<strong>for</strong>e sampl<strong>in</strong>g.<br />

Phthalic anhydride<br />

85-44-9<br />

6,1 Mixed cellulose ester filter Omega M-<br />

1,5 100 HPLC-UV 60<br />

IRSST<br />

82-1<br />

083700AF open-face<br />

906 MCE filter-37 open cassette<br />

m-Phthalod<strong>in</strong>itrile<br />

626-17-5<br />

5 Activated charcoal tube 100/50 mg<br />

0,2 20 GC-NPD<br />

OSHA<br />

IMIS2015<br />

Contact <strong>the</strong> IRSST be<strong>for</strong>e sampl<strong>in</strong>g.<br />

Picloram<br />

1918-02-1<br />

10 SKC 225-8-01-1 or 225-8-04 polyv<strong>in</strong>yl 1,5 180 Grav 25 4,9 IRSST<br />

48-1<br />

chloride filter<br />

902 PVC filter-37<br />

914 PVC filter-25<br />

Additional <strong>in</strong><strong>for</strong>mation is available <strong>in</strong> Info-Labo 91-03. The weight measurement<br />

method <strong>for</strong> dusts is by def<strong>in</strong>ition non-specific.

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