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Sampling Guide for Air Contaminants in the Workplace - Irsst

Sampling Guide for Air Contaminants in the Workplace - Irsst

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Substances non regulated from ROHS<br />

Yellow section <strong>in</strong> <strong>the</strong> orig<strong>in</strong>al document<br />

136<br />

Name<br />

CAS<br />

<strong>Sampl<strong>in</strong>g</strong> device<br />

Flow<br />

L/m<strong>in</strong><br />

Volume<br />

Pr<strong>in</strong>ciple<br />

MRV<br />

µg<br />

CVa<br />

%<br />

#<br />

meth.<br />

Remarks<br />

N-Nitrosopipérid<strong>in</strong>e<br />

100-75-4<br />

Florisil tube 500 mg with pre-tube<br />

2210 Florisil tube with pre-tube<br />

1-2 1000 GC-NPD 0,04 4,3<br />

IRSST<br />

371<br />

The recommended sampl<strong>in</strong>g volume is 400 to 1000 litres. The samples can be<br />

kept <strong>for</strong> 4 weeks <strong>in</strong> <strong>the</strong> dark at 4°C.The simulltaneous determ<strong>in</strong>ation of 8<br />

nitrosam<strong>in</strong>es can be done on <strong>the</strong> same tube.<br />

N-Nitrosopyrrolid<strong>in</strong>e<br />

930-55-2<br />

Florisil tube 500 mg with pre-tube<br />

2210 Florisil tube with pre-tube<br />

1-2 1000 GC-NPD 0,04 3,7<br />

IRSST<br />

371<br />

The recommended sampl<strong>in</strong>g volume is 400 to 1000 litres. The samples can be<br />

kept <strong>for</strong> 4 weeks <strong>in</strong> <strong>the</strong> dark at 4°C.The simulltaneous determ<strong>in</strong>ation of 8<br />

nitrosam<strong>in</strong>es can be done on <strong>the</strong> same tube.<br />

Phenanthrene<br />

85-01-8<br />

Millipore AP4003705 glass fiber filter<br />

pretreated <strong>in</strong> <strong>the</strong> laboratory <strong>in</strong> series with<br />

a Supelco 2-0264 Orbo-42 tube<br />

2187 Orbo 42 100/50 mg<br />

911 GF filter-37<br />

2 960 GC-MS 0,12<br />

IRSST<br />

225-2<br />

The sampl<strong>in</strong>g tra<strong>in</strong> consists of a cassette that will collect <strong>the</strong> PAHs <strong>in</strong> particulate<br />

<strong>for</strong>m, followed by a tube that will adsorb <strong>the</strong> PAHs <strong>in</strong> vapour <strong>for</strong>m. This tube is<br />

connected directly to <strong>the</strong> pump by Tygon tub<strong>in</strong>g. After sampl<strong>in</strong>g, <strong>the</strong> samples<br />

must be stored <strong>in</strong> <strong>the</strong> freezer protected from light. The tubes and filters must be<br />

shipped toge<strong>the</strong>r. Ten hydrocarbons are determ<strong>in</strong>ed simultaneously:<br />

acenaph<strong>the</strong>ne, fluorene, phenanthrene, anthracene, fluoran<strong>the</strong>ne, pyrene,<br />

chrysene, benz(a)anthracene, benzo(e)pyrene et le benzo(a)pyrene.<br />

Propionaldehyde 123-38-6<br />

Supelco 2-0257 Orbo 23 tube<br />

2186 Orbo 23 120/60 mg<br />

0,1 10 GC-MS 0,04<br />

IRSST<br />

323-1<br />

Be<strong>for</strong>e and after sampl<strong>in</strong>g, tubes must be stored <strong>in</strong> a freezer.<br />

Eleven aldehydes are determ<strong>in</strong>ed simultaneously: acetaldehyde,<br />

isobutyraldehyde, isovaleraldehyde, propionaldehyde, butyraldehyde, furfural,<br />

heptanal, hexanal, valeraldehyde, acrole<strong>in</strong> and <strong>for</strong>maldehyde. This method must<br />

not be used <strong>for</strong> <strong>the</strong> specific evaluation of <strong>for</strong>maldehyde; <strong>the</strong> methods to be used<br />

<strong>in</strong> this case are 295-1 and 357-1.<br />

Pyrene 129-00-0<br />

Millipore AP4003705 glass fiber filter<br />

pretreated <strong>in</strong> <strong>the</strong> laboratory <strong>in</strong> series with<br />

a Supelco 2-0264 Orbo-42 tube<br />

2187 Orbo 42 100/50 mg<br />

911 GF filter-37<br />

2 960 GC-MS 0,12<br />

IRSST<br />

225-2<br />

The sampl<strong>in</strong>g tra<strong>in</strong> consists of a cassette that will collect <strong>the</strong> PAHs <strong>in</strong> particulate<br />

<strong>for</strong>m, followed by a tube that will adsorb <strong>the</strong> PAHs <strong>in</strong> vapour <strong>for</strong>m. This tube is<br />

connected directly to <strong>the</strong> pump by Tygon tub<strong>in</strong>g. After sampl<strong>in</strong>g, <strong>the</strong> samples<br />

must be stored <strong>in</strong> <strong>the</strong> freezer protected from light. The tubes and filters must be<br />

shipped toge<strong>the</strong>r. Ten hydrocarbons are determ<strong>in</strong>ed simultaneously:<br />

acenaph<strong>the</strong>ne, fluorene, phenanthrene, anthracene, fluoran<strong>the</strong>ne, pyrene,<br />

chrysene, benz(a)anthracene, benzo(e)pyrene et le benzo(a)pyrene.<br />

Respirable combustible dust (RCD) Silver filter 25 mm (IRSST #950)<br />

1,7<br />

(nylon)<br />

2,75<br />

(GS3)<br />

1000 Grav<br />

CANMET The reference value <strong>for</strong> respirable combustible dust (RCD) accord<strong>in</strong>g to <strong>the</strong><br />

Regulation respect<strong>in</strong>g occupational health and safety <strong>in</strong> m<strong>in</strong>es is 0.6 mg/m³ (8-<br />

hour time-weigted average).<br />

Sevoflurane<br />

28523-86-6<br />

SKC ST226-81 Anasorb 747 tube<br />

2190 Anasorb 747 140/70 mg<br />

Max:<br />

0,2<br />

3<br />

GC-FID<br />

30 2,5<br />

IRSST<br />

355-1<br />

Sevoflurane must be specifically sampled due to <strong>the</strong> sampl<strong>in</strong>g device used and a<br />

specific desorption solvent.<br />

However, simultaneous sampl<strong>in</strong>g and analysis of desflurane is possible. A<br />

permissible exposure value (of <strong>the</strong> TWA type) of 80 mg/m³ has been proposed by<br />

<strong>the</strong> Swedish National Board of Occupational Safety and Health.<br />

Spores<br />

Cassette <strong>for</strong> spores with EMS 120520<br />

microscope slide<br />

931 Spore trap<br />

15 150 DLM<br />

IRSST<br />

367<br />

Spore counts and identification. The MRV is 13 spores/m³ <strong>for</strong> a sampl<strong>in</strong>g volume<br />

of 150 litres.

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