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FATE OF MERCURY IN THE ARCTIC Michael Evan ... - COGCI

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Fate of Mercury in the Arctic 18<br />

2. Overview<br />

The purpose of this chapter is to give a general background for the rest of this thesis, in order to<br />

understand the approach used to address the scientific questions. The overview should also help<br />

place the results of this work in the context of atmospheric chemistry and importance for the global<br />

mercury cycle and the Kingdom of Denmark, and therefore the Danish Arctic perspective.<br />

2.1 General Mercury<br />

Metallic mercury, Nr. 80 in the periodic system, density 13.5 g/cm 3 has been known since 400<br />

B.C. when a disciple of Aristotle (Theophrastus) described a method of producing what he<br />

described as “liquid silver” by rubbing cinnabar in vinegar. It has since been widely used in<br />

metallurgy and other industrial processes.<br />

As Hg is an element, man can neither create nor destroy it.<br />

Mercury is toxic and the toxicity of mercury vapour and its affects on the central nervous<br />

system has been observed and well known through time, for example, the Romans equivocated<br />

sending someone to work in the mercury mines of Spain as a death sentence. Most have heard of<br />

the “mad hatters”, felt workers who became insane from working with mercury, popularized by<br />

Lewis Carrol (“Alice in Wonderland”).<br />

Mercury use has been found in various cultures as a part of dyes, cosmetics and medicines (e.g.<br />

Ernst and Coon, 2001 or Garvey et al., 2001). Its ancient cultural use can be seen in examples from<br />

the old, new and Asian cultures. For example during the Kofun period (6 th century) Japan, it was<br />

thought that mercury was painted onto the body of a dead person (Yamada et al., 1995).<br />

The world’s largest producer of mercury has been and still is the Almaden area of Spain.<br />

Mercury has always been important to metallurgy. It was mined and sent to the new world for

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