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FATE OF MERCURY IN THE ARCTIC Michael Evan ... - COGCI

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Fate of Mercury in the Arctic 6<br />

accumulation rates have since declined with the value for 1995, 14 µg m -2 yr -1 comparable to those<br />

values published in 1995 from the Danish Eulerian Hemispheric Model (Christensen et al., 2002,<br />

Skov et al., 2003, Appendix C), of 12 µg m -2 yr -1 for southern Greenland.<br />

In Denmark, the greatest rate of atmospheric Hg accumulation is found in 1953, 184 µg m -2 yr -<br />

1 , comparable to that of Greenland with the flux going into sharp decline, with an accumulation rate<br />

for 1994 as 14 µg m -2 yr -1 . This compares well with the modelled rate of 18 µg m -2 yr -1 for all of<br />

Denmark. On the Faroe Islands, the maximum mercury concentration was 498 ng g -1 . Dated to be<br />

in 1954 +/-2, with a 210 Pb constant rate of supply dating model, in good agreement with historical<br />

maximums in 1953 in S. Greenland and Denmark. Depositional maximum was in 1985, 34.3 µg m -2<br />

yr -1 , with the 1995 value of 18 µg m -2 yr -1 , comparing with Denmark and the modelled value of<br />

approximately 10 µg m -2 yr -1 . The present day value of approximately 10 µg m -2 yr -1 compares well<br />

with recently reported measurements of 7 µg m -2 yr -1 (Daugaard, 2003). Long-term accumulation<br />

rate of mercury in this core was 0.95 ± 0.36 µg m -2 yr -1 for the period of 4200 B.C. to AD 833; n =<br />

61, in agreement with the Danish and South Greenland peat cores, peat cores from Switzerland and<br />

what is known about the global mercury cycle, and what would be expected in a remote area. The<br />

Hg concentrations in the Faroe Islands are higher than those found in cores from other sites, but the<br />

net Hg accumulation rates are comparable.<br />

The depositional records in the peat are in good agreement with what would be predicted:<br />

lower depositional rates at sites further North from European industries; and in agreement with<br />

previous atmospheric measurements that showed that total gaseous mercury in Europe reached an<br />

average annual maximum in the late 1980’s and have been falling since 1990 decreasing globally<br />

by 22% from 1990 - 1994 (Slemr et al., 1995 and references therein). The results are discussed<br />

with respect to the available literature and their potential implication for our understanding of the<br />

global mercury cycle.

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