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FATE OF MERCURY IN THE ARCTIC Michael Evan ... - COGCI

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134 F. Roos-Barraclough et al. / The Science of the Total Environment 292 (2002) 129–139<br />

Fig.1.Hg concentrations measured in both unfertilised and artificially fertilised peat dried at RT, 30, 60, 90 and 105 8C for up to<br />

2 weeks.<br />

at RT and would therefore account for an increase<br />

y1<br />

of only 0.9 ng g , or 2%, during 14 h of air<br />

drying.It is therefore likely that most of the<br />

observed increase stems from error in the bulk<br />

density determination, which was high in this case<br />

due to the presence of ice in the peat.<br />

3.4. Effect of grinding samples<br />

Grinding promotes homogenisation of the sample<br />

by reducing particle size and by mixing.It<br />

also allows a greater mass of sample to be analysed<br />

at one time, as more material can be placed into<br />

each sample vessel.Therefore grinding allows a<br />

more representative value to be obtained.<br />

The average Hg concentration for unground<br />

y1<br />

samples was 47.9"1. 2 ng g (ns5) and the<br />

average for ground samples was 45.2"1.2 ng<br />

y1 g (ns5).It is therefore possible that a slight<br />

loss of Hg occurs on grinding, possibly due to<br />

elevated temperature, coupled with smaller particle

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