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FATE OF MERCURY IN THE ARCTIC Michael Evan ... - COGCI

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Fate of Mercury in the Arctic 67<br />

pg/m 3<br />

pg/m 3<br />

90.00<br />

80.00<br />

70.00<br />

60.00<br />

50.00<br />

40.00<br />

30.00<br />

20.00<br />

10.00<br />

Cold and warm heating Mantles, RGM measurements 2002<br />

Cold heating mantle<br />

Warm heating mantle<br />

0.00<br />

16-apr 17-apr 18-apr 19-apr 20-apr 21-apr 22-apr 23-apr 24-apr 25-apr<br />

Time<br />

Figure 9. Parallel measurements of RGM at Station Nord, Greenland. Warm denuders were +50 0 C cold<br />

denuders were at ambient temperature, approximately -30 0 C each point represents the<br />

averaged concentration of two denuders. Note: Results near 0.00 pg m -3 cover each other, for<br />

cold and warm denuders.<br />

In Figure 9., page 67, it is seen that the annular denuders heated to 50 0 C using the improved<br />

heating caps, give higher RGM concentration values, when RGM concentrations are higher than<br />

approximately 10 pg m -3 and when there is apparently little, 5 pg m -3 or no RGM, the heated or non-<br />

heated denuders report the same amounts. Each point represents the average of parallel<br />

measurements.<br />

Controlling the heating of the denuders is not just important in the field, but as seen from Figure<br />

10., page 68, also important during laboratory analysis. Landis et al., 2002 note the need for coaxial<br />

fans and good insulation to limit the heat escaping from the clamshell denuder oven and warming<br />

the teflon sampling lines connecting the denuder to the charcoal filter on the inlet side, and the<br />

mercury monitor on the outlet side. Figure 10., page 68, is an experiment where a single denuder,

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