LECTURE PHYSICAL CHEMISTRY 3rd EDITION ROBERT G. MORTIMER

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Enthalpy Changes for Irreversible
Processes
Consider an irreversible process that begins
with an equilibrium and ends with an
equilibrium state. To calculate ∆H for such an
irreversible process, we find a reversible
process with the same initial and final states,
calculate ∆H for that process, and assign that
value to the irreversible process, using the fact
that H is a state function.
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