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LECTURE PHYSICAL CHEMISTRY 3rd EDITION ROBERT G. MORTIMER

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2.2. Heat<br />

Joseph Black was the first to distinguish between the<br />

quantity of heat and the “intensity” of heat<br />

(temperature) and to recognize latent heat absorbed<br />

or given off in phase transitions.<br />

Heat Transferred during Temperature Changes<br />

A small amount of heat added to a system is<br />

proportional to its change in temperature of the<br />

system if there is no phase change or chemical<br />

reaction:<br />

where dq is an infinitesimal amount of heat<br />

transferred to the object and dT is a resulting<br />

infinitesimal change in temperature. The<br />

proportionality constant C is called the heat<br />

capacity of the system.<br />

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Collected by Nguyen Thanh Tu Teacher<br />

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