LECTURE PHYSICAL CHEMISTRY 3rd EDITION ROBERT G. MORTIMER

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Duhem established Eq. (4.1-18), which can be
written in the form
The ∆H term dominates at sufficiently low
temperature, but the T∆S term becomes
important and can dominate at sufficiently high
temperature. In many chemical reactions near
room temperature the T∆S term is numerically
less important than the ∆H term, and most
spontaneous chemical reactions are
exothermic
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