LECTURE PHYSICAL CHEMISTRY 3rd EDITION ROBERT G. MORTIMER

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www.daykemquynhon.ucoz.com The entropy changes of the individual gases are given by Eq. (3.3-3): The entropy change of the system is the sum of these quantities: We now express ∆S in terms of the mole fractions. The mole fraction of substance number i is defined by where n is the total amount of all gases, https://plus.google.com/+DạyKèmQuyNhơn Collected by Nguyen Thanh Tu Teacher MailBox : nguyenthanhtuteacher@hotmail.com
www.daykemquynhon.ucoz.com From Eq. (3.3-13) we have so that the entropy change on mixing the ideal gases is This equation applies to the mixing of substances in other kinds of systems besides ideal gases, if the mixing is random. It can be used to calculate the entropy change of mixing of isotopes of a single element. In a later chapter we will show that it can also be used for the entropy of change of mixing of a class of liquid or solid solutions called ideal solutions. https://plus.google.com/+DạyKèmQuyNhơn Collected by Nguyen Thanh Tu Teacher MailBox : nguyenthanhtuteacher@hotmail.com
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Part 1 Thermodynamics and the Macro
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LECTURE PHYSICAL CHEMISTRY 3rd EDITION ROBERT G. MORTIMER

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