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LECTURE PHYSICAL CHEMISTRY 3rd EDITION ROBERT G. MORTIMER

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An infinitesimal change at equilibrium at constant T<br />

and V must obey<br />

The Gibbs energy is at a minimum if processes at<br />

constant T and P are considered. The Helmholtz<br />

energy is at a minimum if processes at constant T<br />

and V are considered. If a simple closed system is at<br />

constant T and P but not yet at equilibrium, a<br />

spontaneous process could possibly increase the<br />

value of A, but must decrease the value of G. If a<br />

simple closed system is at constant T and V but is<br />

not yet at equilibrium, a spontaneous process could<br />

possibly increase the value of G, but must decrease<br />

the value of A.<br />

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