LECTURE PHYSICAL CHEMISTRY 3rd EDITION ROBERT G. MORTIMER

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where k B is Boltzmann’s constant, equal to
R/N Av . The constant S 0 is a constant that we
usually set equal to zero. The task of this
section is to show that the statistical entropy
can be equivalent to the thermodynamic
entropy for a model system. We can prove
that:
where S is the thermodynamic entropy and
where S 0 is a constant that can be taken equal
to zero if that is convenient.
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