LECTURE PHYSICAL CHEMISTRY 3rd EDITION ROBERT G. MORTIMER

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www.daykemquynhon.ucoz.com 7. The third law of thermodynamics allows the entropy of any pure perfect crystalline substance consistently to be set equal to zero at absolute zero of temperature. 8. The second and third laws of thermodynamics imply that zero temperature on the Kelvin scale is unattainable. https://plus.google.com/+DạyKèmQuyNhơn Collected by Nguyen Thanh Tu Teacher MailBox : nguyenthanhtuteacher@hotmail.com
www.daykemquynhon.ucoz.com 3.1. The Second Law of Thermodynamics and the Carnot Heat Engine The statement of the first law of thermodynamics defines the internal energy and asserts as a generalization of experiment fact that it is a state function. The second law of thermodynamics establishes the entropy as a state function, but in a less direct way. Physical Statements of the Second Law There are two important physical statements of the second law of thermodynamics. - The Kelvin statement is: it is impossible for a system to undergo a cyclic process that turns heat completely into work done on the surroundings. https://plus.google.com/+DạyKèmQuyNhơn Collected by Nguyen Thanh Tu Teacher MailBox : nguyenthanhtuteacher@hotmail.com
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Part 1 Thermodynamics and the Macro
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LECTURE PHYSICAL CHEMISTRY 3rd EDITION ROBERT G. MORTIMER

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