LECTURE PHYSICAL CHEMISTRY 3rd EDITION ROBERT G. MORTIMER

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The left-hand side of Eq. (4.4-7) is equal to
RTln(f/P◦), so that if f ' denotes the fugacity at
pressure P ', we can combine the two integrals
to write
which is the same as
The integrand of this integral is small if the
deviation from ideality is small and vanishes
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if the gas is ideal.
Collected by Nguyen Thanh Tu Teacher
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