LECTURE PHYSICAL CHEMISTRY 3rd EDITION ROBERT G. MORTIMER

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www.daykemquynhon.ucoz.com The partial derivative (∂U/∂V) T ,n is an important measure of the deviation of a system from ideal gas behavior. It has the same units as pressure and is known as the internal pressure. If the internal pressure is positive, the energy increases as the volume increases and work is done against the attractive intermolecular forces. The internal pressure is a measure of the net cohesive forces of the system and can have a large positive value for liquids. To derive a useful equation for the internal pressure, we begin with Eq. (4.3-2) and apply the cycle rule to the partial derivative on the right-hand side of the equation: https://plus.google.com/+DạyKèmQuyNhơn Collected by Nguyen Thanh Tu Teacher MailBox : nguyenthanhtuteacher@hotmail.com
www.daykemquynhon.ucoz.com where α is the coefficient of thermal expansion and κ T is the isothermal compressibility. https://plus.google.com/+DạyKèmQuyNhơn Collected by Nguyen Thanh Tu Teacher MailBox : nguyenthanhtuteacher@hotmail.com
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LECTURE PHYSICAL CHEMISTRY 3rd EDITION ROBERT G. MORTIMER

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