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LECTURE PHYSICAL CHEMISTRY 3rd EDITION ROBERT G. MORTIMER

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www.daykemquynhon.ucoz.com<br />

4. The mathematical statement of the second law<br />

provides a means of calculating the entropy change<br />

of any process that begins and ends at equilibrium<br />

states.<br />

5. The second law implies that no macroscopic<br />

process can decrease the entropy of the universe.<br />

6. Entropy is connected with lack of information<br />

through the Boltzmann definition of the statistical<br />

entropy:<br />

where k B is Boltzmann’s constant and Ω is the<br />

number of mechanical states that corresponds to the<br />

thermodynamic state of the system, corresponding<br />

to a fixed energy.<br />

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Collected by Nguyen Thanh Tu Teacher<br />

MailBox : nguyenthanhtuteacher@hotmail.com

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