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LECTURE PHYSICAL CHEMISTRY 3rd EDITION ROBERT G. MORTIMER

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The two factors in each term of the sum in Eq. (5.1-7)<br />

must be of opposite signs:<br />

- This result can be summarized: At constant<br />

temperature and pressure, any substance tends to<br />

move spontaneously from a phase of higher chemical<br />

potential to a phase of lower chemical potential.<br />

- The fundamental fact of phase equilibrium for<br />

nonuniform systems can be stated: In a system with<br />

uniform temperature and pressure, any substance<br />

tends to move from a region of higher chemical<br />

potential to a region of lower chemical potential.<br />

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Collected by Nguyen Thanh Tu Teacher<br />

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