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LECTURE PHYSICAL CHEMISTRY 3rd EDITION ROBERT G. MORTIMER

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We apply the Maxwell relation of Eq. (4.2-18) to the<br />

first term to obtain<br />

The relation shown in Eq. (4.3-2) is called the<br />

thermodynamic equation of state. For an ideal gas,<br />

so that<br />

It is now necessary only to specify that PV = nRT to<br />

define an ideal gas.<br />

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