LECTURE PHYSICAL CHEMISTRY 3rd EDITION ROBERT G. MORTIMER

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The value of the ratio q 3 /q 1 in a Carnot cycle
therefore depends only on the temperatures of the
reservoirs and not on their composition. The
thermodynamic temperature, θ, is defined by
where θ c is the thermodynamic temperature of the
cold reservoir and θ h is the thermodynamic
temperature of the hot reservoir. We require the
thermodynamic temperature to be positive. The
Carnot efficiency is now given by
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